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Structure of adducts of bis(trifluoromethyl)ketene with methoxymethylamines and diaminomethanes

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    By means of the IR, NMR, and mass spectra of the reaction products of alkoxymethylamines and diaminomethanes with bis(trifluoromethyl)ketene it was shown that these adducts are formed via addition to the C=C bond of the starting ketene.

  2. 2.

    The counter synthesis of the esters ofα-morpholinomethylhexafluoroisobutyric acid was accomplished by the Mannich condensation of the esters ofα-hydrohexafluoroisobutyric acid with methoxy-methylm rpholine.

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Literature cited

  1. R. G. Kostyanovskii, Z. E. Samoilova, and I. I. Chervin, Dokl. Akad. Nauk SSSR,186, 835 (1969).

    Google Scholar 

  2. M. V. Urushadze, E. G. Abduganiev, E. M. Rokhlin, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 1347 (1972).

  3. Yu. A. Cheburkov, N. Mukhamadaliev, and I. L. Knunyants, Izv. Akad. Nauk SSSR, Ser. Khim., 2115 (1966).

  4. I. L. Knunyants, E. G. Abduganiev, S. T. Kocharyan, M. V. Urushadze, V. A. Livshits, Yu. E. Aronov, and E. M. Rokhlin, Izv. Akad. Nauk SSSR, Ser. Khim., 110 (1971).

  5. C. G. Krespan, Tetrahedron,23, 4243 (1967).

    Google Scholar 

  6. N. Muller, R. C. Lauterbur, and G. F. Svatos, J. Amer. Chem. Soc.,79, 1807 (1957); J. W. Emsley, J. Feeney, and L. H. Sutcliffe, High Resolution Nuclear Magnetic Resonance Spectroscopy [Russian translation], Vol. 2, Mir (1969), p. 272.

    Google Scholar 

  7. R G. Kostyanovskii, T. Z. Papoyan, and I. I. Chervin, Izv. Akad. Nauk SSSR, Ser. Khim., 2399 (1968).

  8. R. I. Koshar, T. C. Simmons, and F. W. Hoffmann, J. Amer. Chem. Soc.,79, 1741 (1957).

    Google Scholar 

  9. Z. E. Samoilova, Yu. V. Zeifman, and R. G. Kostyanovskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2621 (1968).

  10. Yu. V. Zeifman, V. V. Tyuleneva, and I. L. Knunyants, Dokl. Akad. Nauk SSSR,201, 1359 (1971).

    Google Scholar 

  11. H. Eck, H. Prigge, and H. Spes, Ann. Chem.,733, 101 (1970).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    M. V. Urushadze, E. G. Abduganiev, Z. E. Samoilova, Kh. Khafizov, E. M. Rokhlin & R. G. Kostyanovskii

  2. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    M. V. Urushadze, E. G. Abduganiev, Z. E. Samoilova, Kh. Khafizov, E. M. Rokhlin & R. G. Kostyanovskii

Authors
  1. M. V. Urushadze
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  2. E. G. Abduganiev
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  3. Z. E. Samoilova
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  4. Kh. Khafizov
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  5. E. M. Rokhlin
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  6. R. G. Kostyanovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 1, pp. 176–179, January, 1973.

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Urushadze, M.V., Abduganiev, E.G., Samoilova, Z.E. et al. Structure of adducts of bis(trifluoromethyl)ketene with methoxymethylamines and diaminomethanes. Russ Chem Bull 22, 182–184 (1973). https://doi.org/10.1007/BF00854158

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  • DOI: https://doi.org/10.1007/BF00854158

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