Conclusions
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1.
It was shown that it is theoretically possible to direct the reaction for the direct synthesis of alkylhalogermanes toward the preferential formation of trialkylhalogermanes.
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2.
Aluminum and gallium most effectively facilitate the formation of trialkylhalogermanes in the direct synthesis reaction.
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3.
The optimum conditions were found for the preparation of trimethylgermane, under which conditions its amount in the condensate reaches 85%, with a total yield of 35%.
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G. Ya. Zueva, A. G. Pogorelov, V. I. Pisarenko, A. D. Snegova, and V. A. Ponomarenko, Izv. Akad. Nauk SSSR, Ser. Neorgan. Mater.,2, 1359 (1967).
K. Moedritzer, J. Organometal. Chem.,21, 1385 (1968).
G. Ya. Zueva, N. V. Luk'yankina, and V. A. Ponomarenko, Izv. Akad. Nauk SSSR, Ser. Khim., 192 (1967).
G. Ya. Zueva, N. V. Luk'yankina, and V. A. Ponomarenko, Izv. Akad. Nauk SSSR, Ser. Khim., 656 (1971).
V. F. Mironov and T. K. Gar, Organic Germanium Compounds [in Russian], Nauka (1965), p. 170.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2777–2781, December, 1971.
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Zueva, G.Y., Luk'yankina, N.V. & Ponomarenko, V.A. Study of the direct synthesis of alkylhalogermanes. Russ Chem Bull 20, 2633–2637 (1971). https://doi.org/10.1007/BF00853639
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DOI: https://doi.org/10.1007/BF00853639