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Synthesis and some reactions of (α-tert-butyldioxyethoxy) diethylthallium

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction of triethylthallium withα-tert-butyldioxyethanol gives (α-tert-butyldioxyethoxy)-diethylthallium (BEDET).

  2. 2.

    BEDET — an organometallic peroxy compound — decomposes with the cleavage of the oxygen-oxygen bond on being heated in benzene, toluene, isopropyl bromide, and tert-butyl bromide, forming diethylthallium acetate and tert-butanol.

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Literature cited

  1. G. A. Razuvaev, E. V. Mitrofanova, and V. A. Dodonov, Dokl. Akad. Nauk SSSR,182, 1342 (1968).

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  2. G. A. Razuvaev, E. V. Mitrofanova, and V. A. Dodonov, Dokl. Akad. Nauk SSSR,187, 1072 (1969).

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  3. S. E. Birch, J. Chem. Soc.,1934, 1132.

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Authors and Affiliations

  1. Polymer Stabilization Laboratory, Academy of Sciences of the USSR, USSR

    G. A. Razuvaev, E. V. Mitrofanova, V. A. Dodonov & L. N. Mol'kova

Authors
  1. G. A. Razuvaev
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  2. E. V. Mitrofanova
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  3. V. A. Dodonov
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  4. L. N. Mol'kova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 465–466, February, 1970.

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Razuvaev, G.A., Mitrofanova, E.V., Dodonov, V.A. et al. Synthesis and some reactions of (α-tert-butyldioxyethoxy) diethylthallium. Russ Chem Bull 19, 419–420 (1970). https://doi.org/10.1007/BF00853404

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  • DOI: https://doi.org/10.1007/BF00853404

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