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Reversed-disproportionation reactions of zirconium compounds containing cyclopentadienyl and chelating groups

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    By the reaction of zirconium tetrachloride with zirconium tetraacetylacetonate, tetrakisdibenzoylmethanate, and tetrakis (3-butylacetylacetonate) at definite molar ratios we obtained triacetylacetonatozirconium chloride and the previously unknown bisdibenzoylmethanatozirconium dichloride, bis(3-butylacetylacetonato)zirconium dichloride, and (3-butylacetylacetonato)zirconium trichloride.

  2. 2.

    By the reaction of dicyclopentadienylzirconium dihalides with zirconium tetraacetylacetonate we obtained diacetylacetonatocyclopentadienylzirconium chloride and bromide.

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Literature cited

  1. E. M. Brainina, R. Kh. Freidlina, and A. N. Nesmeyanov, Izv. AN SSSR. Otd. khim. n.,1958, 937.

  2. R. Kh. Freidlina, E. M. Brainina, and A. N. Nesmeyanov, Dokl. AN SSSR,138, 1369 (1961).

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  3. R. Kh. Freidlina, E. M. Brainina, and A. N. Nesmeyanov, Izv. AN SSSR. Otd. khim. n.,1957, 43.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences, USSR

    E. M. Brainina & R. Kh. Freidlina

Authors
  1. E. M. Brainina
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  2. R. Kh. Freidlina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8 pp. 1421–1425, August, 1964

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Brainina, E.M., Freidlina, R.K. Reversed-disproportionation reactions of zirconium compounds containing cyclopentadienyl and chelating groups. Russ Chem Bull 13, 1331–1334 (1964). https://doi.org/10.1007/BF00850329

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  • DOI: https://doi.org/10.1007/BF00850329

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