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Glycopeptides Communication 14. Synthesis of O-(Amino-Acyl) derivatives of arabinose and mannitol

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The previously developed carbodiimide method was extended to the synthesis of 5-O- and 4-O-[N-(benzyloxycarbonyl)glycyl]-D-mannitol.

  2. 2.

    By the periodate oxidation of 3-O-[N-(benzyloxycarbonyl)glycyl]-D-glucose or its 4,6-O-benzylidene derivative 2-O-[N-(benzyloxycarbonyl)glycyl-D-arabinose was obtained.

  3. 3.

    By the hydrogenolysis of the O-[(benzyloxycarbonyl) amino acyl] derivatives in presence of oxalic acid the corresponding P-(amino-acyl) derivatives were obtained as oxalates.

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Authors and Affiliations

  1. Institute of Chemistry of Natural Products, Academy of Sciences, USSR

    V. A. Derevitskaya, L. M. Likhosherstov & N. K. Kochetkov

Authors
  1. V. A. Derevitskaya
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  2. L. M. Likhosherstov
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  3. N. K. Kochetkov
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Additional information

Translated from Izv.estiya Akademii Nauk SSSR, Seriya Khimicheskaya, pp. 1772–1779, No. 10, October, 1966.

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Derevitskaya, V.A., Likhosherstov, L.M. & Kochetkov, N.K. Glycopeptides Communication 14. Synthesis of O-(Amino-Acyl) derivatives of arabinose and mannitol. Russ Chem Bull 15, 1711–1717 (1966). https://doi.org/10.1007/BF00848708

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  • DOI: https://doi.org/10.1007/BF00848708

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