Summary
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1.
Preparative methods were developed for the synthesis of chloro-, brorno-, iodo-, and fluoro-trimethylgermanes from tetramethylgermane.
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2.
A number of organogermanium compounds were prepared from these halotrimethylgermanes.
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Literature cited
E. G. Rochow, J. Amer. Chem. Soc.,70, 436 (1948).
R. West, H. Hunt, and R. O. Whipple, J. Amer. Chem. Soc.,76, 310 (1954).
V. A. Ponomarenko and G. Ya. Vzenkova, Izv. AN SSSR. Otd. Khim. N.,1957, 994.
M. Schmidt and J. Ruidisch, Z. anorgan. und allgem. Chem.,311, 331 (1961).
B. M. Gladshtein, V. V. Rodé, and L. Z. Soborovskii, Zh. Obshch. Khimii,29, 2155 (1959).
J. E. Griffiths and M. Onysrchuk, Canad. J. Chem.,39, 339 (1961).
L. M. Dennis and W. J. Patnode, J. Amer. Chem. Soc.,53, 2779 (1930).
M. P. Brown and G. W. A. Fowles, J. Chem. Soc.,1958, 2811.
N. S. Vyazankin, G. A. Razuvaev, and O. S. D'yachkovskaya, Zh. Obshch. Khimii,33, 613 (1963).
M. G. Voronkov and B. N. Dolgov, Zh. Obshch. Khimii,24, 1082 (1954).
W. Gillian, R. Meals, and R. Sauer, J. Amer. Chem. Soc.,68, 1161 (1946).
L. I. Zakharkin and V. I. Stanko, Izv. AN SSSR, Otd. Khim. N.,1961, 2079.
V. F. Mironov, A. L. Kravchenko, and L. A. Leites, Izv. AN SSSR. Ser. Khim. (1965).
A. D. Petrov, V. F. Mironov, and D. Mashantsker, Izv. AN SSSR, Otd. Khim. N.,1956, 550.
V. F. Mironov and N. G. Dzhurinskaya, Izv. AN SSSR. Otd. Khim. N.,1963, 75.
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The authors thank L. A. Leites for carrying out the spectral analysis.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1026–1035, June, 1965
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Mironov, V.F., Kravchenko, A.L. Synthesis of organogermanium compounds from tetramethylgermane. Russ Chem Bull 14, 988–995 (1965). https://doi.org/10.1007/BF00845742
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DOI: https://doi.org/10.1007/BF00845742