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Volt-ampere investigation of solutions of N-benzoylphenylhydroxylamine

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A volt-ampere investigation of N-benzoylphenylhydroxylamine (BPHA) on a dropping-mercury electrode has been carried out. In acid solutions the reduction wave for BPHA blends with the reduction wave for H+. Distinct reduction waves were obtained for BPHA on a background of 1 M NH4Cl and in buffer solutions of pH 7.5, Under these conditions the threshold current was proportional to the concentration of BPHA.

  2. 2.

    A volt-ampere investigation of solutions of BPHA with a rotating platinum electrode shows that distinct oxidation waves can be obtained for BPHA only in acid solutions (0.1–10 N H2SO4). Oxidation of BPHA takes place at more positive potentials than oxidation of cupferron.

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Literature cited

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Authors and Affiliations

  1. M. V. Lomonosov Moscow State University, USSR

    I. P. Alimarin, Z. A. Gallai, N. M. Sheina & T. V. Rodionova

Authors
  1. I. P. Alimarin
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  2. Z. A. Gallai
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  3. N. M. Sheina
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  4. T. V. Rodionova
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Alimarin, I.P., Gallai, Z.A., Sheina, N.M. et al. Volt-ampere investigation of solutions of N-benzoylphenylhydroxylamine. Russ Chem Bull 12, 512–514 (1963). https://doi.org/10.1007/BF00844419

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  • DOI: https://doi.org/10.1007/BF00844419

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