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Asymmetrische Katalysen, 86. Mitt.: Enantioselektive Epoxidation von N-Allyl-trichloracetamid mittert-Butylhydroperoxid und Mo-dotierten Y-Zeolithen, Kieselgel, sowie Isopropyltartrat

Asymmetric catalysis, part 86: Enantioselective epoxidation of N-allyltrichloroacetamide withtert-butylhydroperoxide and Mo-doted Y-zeolites, silicagel, as well as isopropyl tartrate

  • Anorganische Und Physikalische Chemie
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Summary

N-Allyl-trichloroacetamide was expoxidized withtert-butylhydroperoxide in toluene to give N-2,3-(epoxypropyl)trichloroacetamide with an enantiomeric excess of up to 43% ee. The enantioselective heterogeneous catalysts used were Mo-doted Y-zeolites and silicagel modified with 2R,3R-(+)-isopropyl tartrate.

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Universität Regensburg, D-93040, Regensburg, Bundesrepublik Deutschland

    H. Brunner & A. Stumpf

Authors
  1. H. Brunner
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  2. A. Stumpf
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Brunner, H., Stumpf, A. Asymmetrische Katalysen, 86. Mitt.: Enantioselektive Epoxidation von N-Allyl-trichloracetamid mittert-Butylhydroperoxid und Mo-dotierten Y-Zeolithen, Kieselgel, sowie Isopropyltartrat. Monatsh Chem 125, 485–489 (1994). https://doi.org/10.1007/BF00811839

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  • DOI: https://doi.org/10.1007/BF00811839

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