Abstract
This work summarizes the most relevant facets of the current knowledge of the principal catalytic processes involved in one carbon-atom conversions. Without doubt, natural gas (or methane) chemical conversion into high molecular weight hydrocarbons via oxidative coupling (OCM) or partial oxidation into C1 oxygenates (POM) currently represents a great chemical and technological challenge for petrochemistry. Although the catalyst systems and the basic principles of the two types of processes are well known, a greater effort is needed towards the development of more efficient and stable catalysts under the severe operation conditions imposed by the reaction itself, as well as the need for suitable reaction design to minimize the extent of the homogeneous reaction. The alternative process is to obtain synthesis gas (CO/H2) in a first step through steam reforming followed by a second Fischer-Tropsch hydrogenation step. However, the unfavorable energetic balance of the reforming step and the absence of selective catalysts in the latter to obtain a narrow molecular weight distribution currently leads to compromise in solutions. Among these, the high molecular weight alcohol synthesis and the recently developed Shell middle distillate synthesis (SMDS) appear to be very attractive. Of no less importance are the reactions which incorporate a CO molecule into alcohols or olefins via carbonylations and hydroformylations. Within this framework, the use of organometallic complexes anchored to functionalized polymeric matrices initiated a very intense research activity, particularly in the development of stable catalysts.
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References
M.J. Brown and N.D. Parkyns, Catal. Today 8 (1991) 305.
R.L. Pruett, Science 211 (1981) 11.
E.L. Muetterties and J. Stein, Chem. Rev. 79 (1979) 479.
K. Klier, Adv. Catal. 31 (1982) 243.
J.S. Lee and S.T. Oyama, Catal. Rev.-Sci. Eng. 30 (1988) 249.
P. Chaumette, Ph. Courty, J.A. Dalmon, C. Mirodatos, G.A. Martin, P. Meriaudeau, J. Hubert, H. Noels, A. Kiennemann and R. Kieffer, in:Progr. Synth. Fuels, eds. G. Imarisio and J.M. Bemtgen (EEC, 1988) p. 58.
S. Vic, J.P. Gómez, J.M. Jiménez, M.A. Peña, P. Terreros and J.L.G. Fierro, to be published.
M.J. van der Burgt, C.J. van Leeuwen, J.J. Dell'Amico and S.T. Sie, in:Methane Conversion, eds. D.M. Bibby, C.D. Chang, R.F. Howe and S. Yurchak (Elsevier, Amsterdam, 1988) p. 473;
I.E. Maxwell and J.E. Naber, Catal. Lett. 12 (1992) 105.
C.D. Chang and A.J. Silvestri, CHEMTECH (October 1978) 624.
R. Pitchai and K. Klier, Catal. Rev.-Sci. Eng. 28 (1986) 13.
G.E. Keller and M.M. Bhasin, J. Catal. 73 (1982) 9.
W. Hinsen and M. Baerns, Chem. Z. 107 (1983) 223.
W. Hinsen, W. Bytyn and M. Baerns, in:Proc. 8th Int. Congr. on Catalysis, Vol. 3, Berlin 1984 (Verlag Chemie, Weinheim, 1984) p. 581.
T. Ito and J.H. Lunsford, Nature 314 (1985) 721.
C.A. Jones, J.J. Leonard and J.A. Sofranko, US Patents 4,443,644; 4,443,645; 4,443,646; 4,443,647; 4,443,648; 4,443,649; 4,444, 948 (1984); 4,448,322; 4,448,323; 4,523,049; 4,523,050 (1985); 4,567,307 (1986).
Kh. Minachev, N.Ya. Usachev, Yu.S. Khodakov, L.L. Kozlov, V.N. Udut and O.A. Fomin, Bull. Acad. Sci. URSS 36 (1987) 456.
T.R. Baldwin, R. Burch, E.M. Crabb, G.D. Squire and S.C. Tsang, Appl. Catal. 56 (1989) 219.
J.A. Labinger and K.C. Ott, J. Phys. Chem. 91 (1987) 2682.
S. Ahmed and J.B. Moffat, Catal. Lett. 2 (1989) 309.
M.Yu. Sinev, G.A. Vorob'eva and V.N. Korchak, Kinet. Katal. 27 (1987) 1007.
J.M. Thomas, X. Kwan and J. Stachirski, J. Chem. Soc. Chem. Commun. 22 (1988) 20.
K. Asami, T. Shikada, K. Fujimoto and H. Tominaga, Ind. Eng. Chem. Res. 26 (1987) 2348.
S.K. Agarwall, R.A. Migone and G. Marcellin, J. Catal. 121 (1990) 110.
D.J. Driscoll, W. Martir, J.X. Wang and J.H. Lunsford, J. Am. Chem. Soc. 107 (1985) 58.
T. Ito, J.X. Wang, C.H. Lin and J.H. Lunsford, J. Am. Chem. Soc. 107 (1985) 5062.
N.W. Cant, C.A. Lukey, P.F. Nelson and R.J. Tyler, J. Chem. Soc. Chem. Commun. (1988) 766.
J.A. Roos, S.J. Korf, R.H.J. Veehof, J.G. van Ommen and J.R.H. Ross, Appl. Catal. 52 (1989) 147.
C. Mirodatos, G.A. Martin, G.C. Bertolini and J. Saint Just, Catal. Today 4 (1989) 301.
S.J. Korf, J.A. Roos, J.W.H.C. Derksen, J.A. Vreeman, J.G. van Ommen and J.R.H. Ross, Appl. Catal. 59 (1990) 291.
X.D. Peng, D.S. Richards and P.C. Stair, J.Catal. 121 (1990) 90.
N. Yamagata, K. Tanaka, N. Sasaki and S. Okazaki, Chem. Lett. (1987) 81.
E. Iwamatsu, T. Moriyama, N. Takasaki and K. Aika, J. Chem. Soc. Chem. Commun. (1987) 19.
C.H. Lin, K.D. Campbell, J.X. Wang and J.H. Lunsford, J. Phys. Chem. 90 (1986) 534.
K. Otsuka and T. Nakajima, J. Chem. Soc. Faraday Trans. I 83 (1987) 1315.
S. Wada, T. Tagawa and H. Imai, Appl. Catal. 47 (1989) 227.
Z. Kalenik and E.E. Wolf, ACS Symp. Ser. 37 (1992) 117.
A. Ekstrom and J.A. Lapszewicz, J. Phys. Chem. 93 (1989) 5230.
G.J. Hutchings, M.S. Scurrell and R.J. Woodhouse, Catal. Today 4 (1989) 371.
A.M. Gaffney, C.A. Jones, J.J. Leonard and J.A. Sofranko, J. Catal. 114(1988) 422.
S.J. Korf, J.A. Roos, J.M. Diphoorn, R.J.H. Veehof, J.G. van Ommen and J.R.H. Ross, ACS Symp. Ser. 35 (1988) 437.
S.J. Korf, J.A. Roos, J.M. Diphoorn, R.J.H. Veehof, J.G. van Ommen and J.R.H. Ross, Catal. Today 4 (1989) 279.
A. Shamsi and K. Zahir, Energy & Fuels 3 (1989) 727.
T. Sodesawa, M. Matsubara, S. Satoh and F. Nozaki, Chem. Lett. (1987) 1513.
J.M. De Boy and R.F. Hicks, Ind. Eng. Chem. Res. 27 (1988) 1577.
J.M. De Boy and R.F. Hicks, J. Catal. 113 (1988) 517.
R.J. Tyler and C.A. Lukey, ACS Symp. Ser., Preprints 32 (1987) 249.
K.D. Campbell, E. Morales and J.H. Lunsford, J. Am. Chem. Soc. 109 (1987) 7900.
Q. Li and Y. Amenomiya, Appl. Catal. 23 (1986) 173.
I.T. Ali Emesh and Y. Amenomiya, J. Phys. Chem. 90 (1986) 4785.
P.F. Nelson, C.A. Lukey and N.W. Cant, J. Phys. Chem. 92 (1988) 6176.
P.F. Nelson and N.W. Cant, J.Phys. Chem. 94 (1990) 3756.
J. Warnatz, in:18th Int. Combustion Symp. (The Combustion Institute, Pittsburgh, 1981) p. 369.
J. Warnatz, in:Combustion Chemistry, ed. W.C. Gardiner, (Springer, Berlin, 1984) p. 197.
H. Zanthoff and M. Baerns, Ind. Eng. Chem. Res. 29 (1990) 2.
J.C. Mackie, J.G. Smith, P.F. Nelson and R.J. Tyler, Energy & Fuels 4 (1990) 277.
N.R. Hunter, H.D. Gesser, L.A. Morton, P.S. Yarlagadda and D.P.C. Fung, Appl. Catal. 57 (1990) 45.
R. Burch, G.D. Squire and S.C. Tsang, J. Chem. Soc. Faraday Trans. I 85 (1989) 3561.
K. Otsuka and M. Hatano, J. Catal. 108 (1987) 252.
N.D. Spencer, J. Catal. 109 (1988) 187.
M.A. Banares and J.L.G. Fierro, An. Quím. 87 (1991) 223.
N.D. Spencer and C.J. Pereira, J. Catal. 116 (1989) 399.
M.A. Banares and J.L.G. Fierro, Am. Chem. Soc., Petr. Chem. Div. 37 (1992) 1171.
M.A. Banares and J.L.G. Fierro, Catal. Lett. 17 (1993) 205.
A. Parmaliana, F. Frusteri, D. Miceli, A. Mezzapica, M.S. Scurrell and N. Giordano, Appl. Catal. 78 (1991) L7.
A. Parmaliana, V. Sokolovskii, D. Miceli, F. Arena and N. Giordano, Am. Chem. Soc., Petr. Chem. Div. 7 (1992) 1076.
Q. Sun, J.I. Di Cosimo, R.G. Herman, K. Klier and M.M. Bhasin, Catal. Lett. 15 (1992) 371.
T. Yamaguchi, E. Echigoya, S. Say and M. Sueyoshi, Japan. Patent JP 62-212336 (1987).
V. Amir-Ebrahimi and J.J. Rooney, J. Mol. Catal. 50 (1989) L17.
M.A. Bañares and J.L.G. Fierro, unpublished.
T. Suzuki, K. Wada, M. Shima and Y. Watanabe, J. Chem. Soc. Chem. Commun. (1990) 1059.
T.J. Yang and J.H. Lunsford, J. Catal. 103 (1987) 55.
M.A. Bañares, I. Rodríguez-Ramos, A. Guerrero-Ruíz and J.L.G. Fierro, in:New Frontiers in Catalysis, Vol. A, eds. L. Guczi, F. Solymosi and F. Tetenyi (Akadémiai Kiadó, Budapest, 1993) p. 1131.
J.N. Armor, Appl. Catal. 49 (1989) 1.
K. Omata, S. Hashimoto, H. Tominaga and K. Fujimoto, Appl. Catal. 52 (1989) L1.
H.H. Storch, N. Golumbic and R.B. Anderson,The Fischer-Tropsch and Related Syntheses (Wiley, New York, 1951).
Ya.T. Eidus, Russ. Chem. Rev. 36 (1967) 338.
M.A. Vannice, Catal. Rev.-Sci. Eng. 14 (1976) 153.
G. Henrici-Olivé and S. Olive, Angew. Chem. Int. Ed. 15 (1976) 136.
V. Ponec, Catal. Rev.-Sci. Eng. 18 (1978) 151.
C.K. Rofer-dePoorter, Chem. Rev. 81 (1981) 447.
R.B. Anderson, in:Catalysis Vol.4, ed. P.H. Emmett (Reinhold, New York, 1956).
P. Forzatti, E. Tronconi and I. Pasquon, Catal. Rev.-Sci. Eng. 33 (1991) 109.
L.G. Tejuca, J.L.G. Fierro and J.M.D. Tascón, Adv. Catal. 36 (1989) 237.
J.L.G. Fierro, Catal. Rev.-Sci. Eng. 34 (1992) 321; in:Properties and Applications of Perovskite-Type Oxides, eds. L.G. Tejuca and J.L.G. Fierro (Dekker, New York, 1993) ch. 12.
J.I. Di Cosimo, A.J. Marchi and C.R. Apesteguia, J. Catal. 134 (1992) 594.
R. Szimanski, C. Travers, P. Chaumette, Ph. Courty and D. Durand, in:Preparation of Catalysts IV, eds. B. Delmon, P. Grange, P.A. Jacobs and G. Poncelet (Elsevier, Amsterdam, 1987) p. 738.
Ph. Courty, D. Durand, E. Freund and A. Sugier, J. Mol. Catal. 17 (1982) 241.
F. Cavani, F. Trifiro and A. Vaccari, Catal. Today 11 (1991) 173.
J.G. Nunan, R.G. Herman and K. Klier, J. Catal. 116 (1989) 222.
J.G. Nunan, C.E. Bogdan, K. Klier, K.J. Smith, C.W. Young and R.G. Herman, J. Catal. 116 (1989) 195.
K.J. Smith and R.B. Anderson, Can. J. Chem. Eng. 61 (1983) 40.
K.J. Smith and R.B. Anderson, J. Catal. 85 (1984) 428.
D.J. Elliott and F. Pennella, J. Catal. 119 (1989) 359.
J.A. Broussard and L.E. Wade, Am. Chem. Soc., Div. Fuel Chem. 31 (1986) 75.
J.A. Brown-Bourzutschky, N. Homs and A.T. Bell, J. Catal. 124 (1990) 52.
M.L. Rojas and J.L.G. Fierro, J. Solid State Chem. 89 (1990) 299.
M.L. Rojas, J.L.G. Fierro, L.G. Tejuca and A.T. Bell, J. Catal. 124 (1990) 41.
R. van Grieken, J.L. Pena, A. Lucas, G. Calleja, M.L. Rojas and J.L.G. Fierro, Catal. Lett. 8 (1991) 335.
G.R. Sheffer and T.S. King, J. Catal. 115 (1989) 376.
G. Broden, T.N. Rhodin, C. Brucker, R. Brendow and Z. Hurych, Surf. Sci. 59 (1976) 593.
V.N. Zudin, V.A. Likholobov, Yu.I. Ermakov and N.K. Eremenko, Kinet. Katal. 18 (1977) 524.
V.N. Zudin, V.A. Likholobov and Yu.I. Ermakov, Kinet. Katal. 20 (1979) 1599.
E.C. Blossey and D.C. Neckers, in:Solid Phase Synthesis (Hutchinson and Ross, Dowden 1975).
B. Cornus, in:New Syntheses with Carbon Monoxide, ed. J. Falbe (Springer, Berlin, 1980) p. 1.
R.B. King and R.M. Hanes, J. Org. Chem. 44 (1979) 1092.
B.C. Gates,Catalytic Chemistry (Wiley, New York, 1992).
P. Terreros, E. Pastor and J.L.G. Fierro, J. Mol. Catal. 5 (1989) 359.
P. Terreros, E. Pastor, J.M. Palacios and J.L.G. Fierro, Surf. Interface Anal. 15 (1990) 279.
A. Guerrero-Ruíz, I. Rodríguez-Ramos and J.L.G. Fierro, Appl. Catal. 72 (1991) 119.
I. Rodríguez-Ramos, A. Guerrero-Ruíz, M.L. Rojas and J.L.G. Fierro, Appl. Catal. 68 (1991) 217.
I. Rodríguez-Ramos, A. Guerrero-Ruíz and J.L.G. Fierro, Am. Chem. Soc. Petrol. Chem. Div. 36 (1991) 804.
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Fierro, J.L.G. Catalysis in C1 chemistry: Future and prospect. Catal Lett 22, 67–91 (1993). https://doi.org/10.1007/BF00811770
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DOI: https://doi.org/10.1007/BF00811770