Abstract
The dipole moments of 1-ethoxy-2-carbasilatrane (1-ethoxy-2,8-dioxa-5-aza-1-silabicyclo [3,3,3]undecane (II)), and of 1,1-dimethyl-2,8-dioxa-5-aza-1-silacyclooctane (III) have been investigated. The presence of a transannular Si ← N coordination bond (weaker than in the 1-ethoxysilatrane 1) in II and its absence from III has been established.
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References
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For part X, see [1].
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Mazheika, I.B., Libert, L.I., Lukevits, E. et al. Nitrogen-containing organosilicon compounds. Chem Heterocycl Compd 4, 415–416 (1968). https://doi.org/10.1007/BF00755304
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DOI: https://doi.org/10.1007/BF00755304