Abstract
The inhibiting effect of dithiolthione derivatives of hydrogenated quinolines (DTT) on the oxidation of various hydrocarbons (n-decane,n-decene, ethylbenzene, β-carotene) was investigated. The inhibiting effect of the DTTs is greater at high temperatures (>100 °C) than that of the parent hydrogenated quinolines and weaker at moderate temperatures. The DTTs do not affect the decomposition of hydroperoxides. Probably, the introduction of a dithiolthione cycle to a hydroquinoline molecule decreases its reactivity toward O2 and peroxide radicals, which favors the enhancement of the antioxidative activity of the DTTs at elevated temperatures.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 814–818, May, 1994.
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Kasaikina, O.T., Golovina, N.A., Shikhaliev, K.S. et al. Kinetic description of the oxidation of hydrocarbons inhibited by sulfur-containing hydrogenated quinolines. Russ Chem Bull 43, 755–759 (1994). https://doi.org/10.1007/BF00717333
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DOI: https://doi.org/10.1007/BF00717333