Abstract
The energies of the charge-transfer bands and the redox potentials of substituted cyanoiron complexes are strongly influenced by preferential solvation effects in water-acetonitrile mixed solvents, exhibiting a linear dependence with respect to the acceptor number scale. The dependence increases with the number of cyanide ligands in the complexes.
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Toma, H.E., Takasugi, M.S. Preferential solvation effects in the electrochemistry and charge-transfer spectra of cyanoiron(II) complexes. J Solution Chem 18, 575–583 (1989). https://doi.org/10.1007/BF00664238
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DOI: https://doi.org/10.1007/BF00664238