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Thermodynamics of electrolytes. X. Enthalpy and the effect of temperature on the activity coefficients

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Abstract

Heat of dilution and of solution data are fitted to the form of equation corresponding to that used successfully for activity and osmotic coefficients over a wide range of concentrations. The resulting parameters give the change with temperature of the activity and osmotic coefficients. Results are reported for 84 electrolytes of 1-1, 2-1, 3-1, and 2-2 valence types.

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Authors and Affiliations

  1. Department of Chemistry and Lawrence Berkeley Laboratory, University of California, 94720, Berkeley, California

    Leonard F. Silvester & Kenneth S. Pitzer

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  1. Leonard F. Silvester
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  2. Kenneth S. Pitzer
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Silvester, L.F., Pitzer, K.S. Thermodynamics of electrolytes. X. Enthalpy and the effect of temperature on the activity coefficients. J Solution Chem 7, 327–337 (1978). https://doi.org/10.1007/BF00662893

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  • DOI: https://doi.org/10.1007/BF00662893

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