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The effect of methyl substitution on the spin-state in solid bis(methyl-substituted 2-pyridinalphenylimine)di(thiocyanato)iron(II)

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Summary

A series of iron(II) complexes of the type [FeL2(NCS)2] have been prepared and characterized, where L denotes the bidentate diimine ligands 2-pyridinalphenylimine orN-phenyl-2-pyridinaldimine (ppi) and its methyl-substituted derivatives. The electronic ground spin-state of iron(II) in these complexes has been studied by means of Mössbauer spectroscopy and magnetic susceptibility measurements.

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Authors and Affiliations

  1. Department of Chemistry, Tamkang University, Tamsui, Taiwan

    Ho-Hsiang Wei, Shih-Ping Kao & Yuch-Cheng Jean

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  1. Ho-Hsiang Wei
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  2. Shih-Ping Kao
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  3. Yuch-Cheng Jean
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Wei, HH., Kao, SP. & Jean, YC. The effect of methyl substitution on the spin-state in solid bis(methyl-substituted 2-pyridinalphenylimine)di(thiocyanato)iron(II). Transition Met Chem 11, 405–408 (1986). https://doi.org/10.1007/BF00623417

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  • DOI: https://doi.org/10.1007/BF00623417

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