Abstract
The13C NMR spectra of a number of α-homologs of 11-deoxyprostaglandin E1 have been investigated and a stereochemical assignment has been made of the diasteromeric pairs of isomers with lengths of the α-chain from seven to twelve carbon atoms. The most informative characteristics for the separation of the classes of epimers have been determined; these are differences in the chemical shifts of the C13 and C15 carbon atoms.
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Additional information
Institute of Chemistry, Bashkir Branch, Academy of Sciences of the USSR, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 315–319, May–June, 1985.
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Tolstikov, G.A., Khalilov, L.M., Panasenko, A.A. et al. 13C NMR spectra of biologically active compounds. I. α-Homologs of 11-deoxyprostaglandin E1 . Chem Nat Compd 21, 293–297 (1985). https://doi.org/10.1007/BF00574196
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DOI: https://doi.org/10.1007/BF00574196