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NMR spectral study of the structure of 2-amino-4-thiazolinones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

As a consequence of partial double bond nature of the exocyclic C-N bond, 2-methylamino-4-thiazolinone exists in DMSO-D6 as a mixture of E and Z conformers of the amino form with predominance of the sterically favored E conformer. 2-Phenylimino-4-thiazolidinone in the same solvent exists as a mixture of the E and Z isomers of the imino form.

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Literature cited

  1. E. Akerblom, Acta Chem. Scand., 21, 1437 (1967).

    Google Scholar 

  2. P. Sohar, G. Feher, and L. Toldy, Org. Magn. Reson., 11, 9 (1978).

    Google Scholar 

  3. G. Toth and A. Almasy, Org. Magn. Reson., 19, 219 (1982).

    Google Scholar 

  4. A. P. Engoyan, E. M. Peresleni, T. F. Vlasova, I. I. Chizhevskaya, and Yu. N. Sheinker, Khim. Geterotsikl. Soedin., No. 2, 190 (1978).

    Google Scholar 

  5. Yu. G. Basova, Chemical Sciences Candidate's Dissertation, Leningrad (1980).

  6. S. M. Ramsh, S. Yu. Solov'eva, and A. I. Ginak, Khim. Geterotsikl. Soedin., No. 6, 761 (1983).

    Google Scholar 

  7. C. L. Perrin, E. R. Johnston, C. R. Lollo, and P. A. Kobrin, J. Am. Chem. Soc., 103, 4691 (1981).

    Google Scholar 

  8. C. F. Howell, W. Fulmor, N. Q. Quinones, and R. A. Hardy, J. Org. Chem., 29, 370 (1964).

    Google Scholar 

  9. H. Shanan-Atidi and K. Bar-Eli, J. Phys. Chem., 74, 961 (1970).

    Google Scholar 

  10. H. Gunther, Introduction to NMR Spectroscopy [Russian translation], Izd. Mir, Moscow (1984), p. 262.

    Google Scholar 

  11. N. N. Khovratovich and I. I. Chizhevskaya, Khim. Geterotsikl. Soedin., No. 4, 637 (1967).

    Google Scholar 

  12. S. M. Ramsh, N. A. Smorygo, and E. S. Khrabrova, Khim. Geterotsikl. Soedin., No. 1, 32 (1985).

    Google Scholar 

  13. S. M. Ramsh, N. A. Smorygo, A. I. Ginak, and E. G. Sochilin, Zh. Org. Khim., 15, 1506 (1979).

    Google Scholar 

  14. A. P. Engoyan, T. F. Vlasova, Yu. N. Sheinker, and I. I. Chizhevskaya, Dokl. Akad. Nauk SSSR, 209, 1099 (1973).

    Google Scholar 

  15. E. Akerblom, Acta Chem. Scand., 21, 843 (1967).

    Google Scholar 

  16. S. M. Ramsh, A. I. Ginak, N. A. Smorygo, Yu. G. Basova, and E. G. Sochilin, Zh. Org. Khim., 14, 1327 (1978).

    Google Scholar 

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Authors and Affiliations

  1. Lensovet Leningrad Technological Institute, 198013, Leningrad

    S. M. Ramsh, N. A. Smorygo, E. S. Khrabrova & A. I. Ginak

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  1. S. M. Ramsh
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  2. N. A. Smorygo
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  3. E. S. Khrabrova
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  4. A. I. Ginak
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Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 544–548, April, 1986.

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Ramsh, S.M., Smorygo, N.A., Khrabrova, E.S. et al. NMR spectral study of the structure of 2-amino-4-thiazolinones. Chem Heterocycl Compd 22, 447–451 (1986). https://doi.org/10.1007/BF00542789

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  • DOI: https://doi.org/10.1007/BF00542789

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