Skip to main content
SpringerLink
Log in

Transport properties of nonelectrolyte liquid mixtures—VI. Viscosimetric study of binary mixtures of hexafluorobenzene with aromatic hydrocarbons

  • Published:
International Journal of Thermophysics Aims and scope Submit manuscript

Abstract

Viscosity coefficients for binary mixtures of hexafluorobenzene with benzene, toluene, para-xylene, and mesitylene have been measured along the saturation line at temperatures from 15 to 120°C using specially designed capillary viscometers. Densities were measured using a pyknometer and volume-change apparatus. Deviations of the viscosities from a rectilinear dependence on mole fraction are consistent with enhanced interactions between unlike species, which increase with increasing number of methyl groups on the aromatic hydrocarbon and decrease with increasing temperature. The application of the Grunberg and Nissan equation, the Hildebrand equation, and energy of activation theories to these results is examined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. R. Patrick and G. S. Prosser, Nature 187:1021 (1960).

    Google Scholar 

  2. W. A. Duncan and F. L. Swinton, Trans. Faraday Soc. 62:1082 (1966).

    Google Scholar 

  3. E. McLaughlin and C. E. Messer, J. Chem. Soc. A 1106 (1966).

    Google Scholar 

  4. J. C. A. Boeyens and F. H. Herbstein, J. Phys. Chem. 69:2153 (1965).

    Google Scholar 

  5. T. Dahl, Acta Chem. Scand. Ser. A A29:699 (1975).

    Google Scholar 

  6. T. Dahl, Acta Chem. Scand. 27:995 (1973).

    Google Scholar 

  7. D. F. R. Gilson and C. A. McDowell, Can. J. Chem. 44:945 (1966).

    Google Scholar 

  8. T. Dahl, Acta Chem. Scand. 26:1569 (1972).

    Google Scholar 

  9. A. D. Bedsole and Z. L. Taylor, Jr., J. Ala. Acad. Sci. 39:270 (1968).

    Google Scholar 

  10. A. K. M. Masood, A. M. North, R. A. Pethrick, M. Towland, and F. L. Swinton, J. Chem. Thermodyn. 9:133 (1977),

    Google Scholar 

  11. D. V. Fenby, I. A. McLure, and R. L. Scott, J. Phys. Chem. 70:6023 (1966).

    Google Scholar 

  12. J. Vrbancich and G. L. D. Ritchie, J. Chem. Soc. Faraday II 76:648 (1980).

    Google Scholar 

  13. A. K. M. Masood, A. M. North, R. A. Pethrick, M. Towland, and F. L. Swinton, Adv. Mol. Relax. Process. 9:153 (1976).

    Google Scholar 

  14. D. A. Bauer, J. I. Brauman, and R. Pecora, J. Chem. Phys. 63:53 (1975).

    Google Scholar 

  15. J. H. Dymond, J. Robertson, and J. D. Isdale, Int. J. Thermophys. 2:223 (1981).

    Google Scholar 

  16. J. H. Dymond, N. Glen, J. Robertson, and J. D. Isdale, J. Chem. Thermodyn. 14:1149 (1982).

    Google Scholar 

  17. J. H. Dymond and K. J. Young, Int. J. Thermophys. 1:331 (1980).

    Google Scholar 

  18. G. D. Wedlake, J. H. Vera, and G. A. Ratcliff, Rev. Sci. Instrum. 50:93 (1979).

    Google Scholar 

  19. Handbook of Chemistry and Physics, 61st ed. (C.R.C. Press, Boca Raton, Fla., 1980–1981).

  20. Selected Values of Properties of Hydrocarbons and Related Compounds, American Petroleum Research Project 44 (Thermodynamic Research Centre, Texas A&M University, College Station, 1948, 1949, 1972).

  21. A. Weissberger, Techniques of Organic Chemistry I. Physical Methods, Vol.I (Interscience, New York, 1959), pp. 85–86.

    Google Scholar 

  22. W. A. Duncan, J. P. Sheridan, and F. L. Swinton, Trans. Faraday Soc. 62:1090 (1966).

    Google Scholar 

  23. J. L. Hales and R. Townsend, J. Chem. Thermodyn. 6:111 (1974).

    Google Scholar 

  24. R. Meyer, A. Barlatier, and J. Metzger, J. Chim. Phys. Physiochim. Biol. 68:417 (1971).

    Google Scholar 

  25. S. S. Chen and B. J. Zwolinski, J. Chem. Thermodyn. 7:251 (1975).

    Google Scholar 

  26. J. L. Hales and R. Townsend, J. Chem. Thermodyn. 4:763 (1972).

    Google Scholar 

  27. F. Kimura and S. Marakami, Fluid Phase Equil. 3:93 (1979).

    Google Scholar 

  28. J. Timmermans, Physico-Chemical Constants of Pure Organic Compounds. Vol. II (Elsevier, Amsterdam, London, New York, 1965).

    Google Scholar 

  29. H. L. Clever and K.-Y. Hsu, J. Chem. Thermodyn. 7:435 (1975).

    Google Scholar 

  30. J. A. Riddick and W. B. Burger, Organic Solvents, Techniques of Chemistry, Vol. II, A. Weissberger, ed. (Wiley Interscience, New York, 1970).

    Google Scholar 

  31. H. L. Clever and K.-Y. Hsu, J. Chem. Thermodyn. 10:213 (1978).

    Google Scholar 

  32. W. Woycicki and K. W. Sadowska, Bull. Acad. Pol. Sci. Ser. Sci. Chim. 16:531 (1968).

    Google Scholar 

  33. Int. Data Ser., Selec. Data Mix. Ser. A 203 (1974).

    Google Scholar 

  34. A. Nissema and A. Kuvaja, Suomen Kemistilehti B 45:206 (1972).

    Google Scholar 

  35. M. J. Mussche and L. A. Verhoeye, J. Chem. Eng. Data 20:46 (1975).

    Google Scholar 

  36. H. M. N. H. Irving and R. B. Simpson, J. Inorg. Nucl. Chem. 34:2241 (1972).

    Google Scholar 

  37. M. S. Medani and M. A. Hasan, Can. J. Chem. Eng. 55:203 (1977).

    Google Scholar 

  38. J. Timmermans, Physico-Chemical Constants of Pure Organic Compounds (Elsevier, New York, Amsterdam, London, Brussels, 1950).

    Google Scholar 

  39. A. Nissema and P. Kokkonen, Finn. Chem. Lett. 1:7 (1979).

    Google Scholar 

  40. P. Kokkonen and A. Nissema, Finn. Chem. Lett. 3:69 (1979).

    Google Scholar 

  41. S. Ruenkrairergsa, D. V. Fenby, and D. E. Jones, J. Chem. Thermodyn. 5:347 (1973).

    Google Scholar 

  42. S. Glasstone, K. J. Laidler, and H. Eyring, Theory of Rate Processes (McGraw-Hill, New York, 1941), Chap. 9.

    Google Scholar 

  43. J. B. Irving, N.E.L. Report No. 631 (National Engineering Laboratory, East Kilbride, Glasgow, 1977).

    Google Scholar 

  44. L. Grunberg and A. H. Nissan, Nature (Lond.) 164:799 (1949).

    Google Scholar 

  45. C. L. Watkins and W. S. Brey, Jr., J. Phys. Chem. 74:235 (1970).

    Google Scholar 

  46. A. J. Batschinski, Z. Physik. Chem. 84:643 (1913).

    Google Scholar 

  47. J. H. Hildebrand, Science 174:490 (1971).

    Google Scholar 

  48. E. Ertl and F. A. L. Dullien, J. Phys. Chem. 77:3007 (1973).

    Google Scholar 

  49. G. L. Bertrand, Ind. Eng. Chem. Fundam. 16:492 (1977).

    Google Scholar 

Download references

Author information

Author notes

  1. J. Robertson

    Present address: Department of Clinical Physics and Bioengineering, 11 West Graham Street, G4 9LF, Glasgow, UK

Authors and Affiliations

  1. Chemistry Department, The University, G12 8QQ, Glasgow, UK

    J. H. Dymond & J. Robertson

Authors
  1. J. H. Dymond
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Robertson
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dymond, J.H., Robertson, J. Transport properties of nonelectrolyte liquid mixtures—VI. Viscosimetric study of binary mixtures of hexafluorobenzene with aromatic hydrocarbons. Int J Thermophys 6, 21–41 (1985). https://doi.org/10.1007/BF00505790

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00505790

Key words

Search

Navigation