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Aziridinyl ketones and their heteroanalogs. 5. Synthesis and structures of 2-aryl-3-aroylaziridines

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

A number of trans- and cis-isomeric 1-R-2-aryl-3-aroylaziridines were synthesized, and their IR spectra were studied. Intramolecular hydrogen bonding is realized in the trans isomers when R = H, and they exist in the only possible conformation (intermediate between a gauche and a cisoid conformation). cis-Isomers II (R = alkyl) exist in solutions in the form of two conformers, viz., gauche and cisoid conformers, and the gauche conformer is thermodynamically preferable.

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Authors and Affiliations

  1. A. M. Gor'kii Kharkov State University, 310077, Kharkov

    V. D. Orlov, F. G. Yaremenko & V. F. Lavrushin

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  1. V. D. Orlov
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  2. F. G. Yaremenko
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  3. V. F. Lavrushin
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Additional information

See [1] for Communication A.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No, 11, pp. 1489–1494, November, 1980.

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Orlov, V.D., Yaremenko, F.G. & Lavrushin, V.F. Aziridinyl ketones and their heteroanalogs. 5. Synthesis and structures of 2-aryl-3-aroylaziridines. Chem Heterocycl Compd 16, 1128–1133 (1980). https://doi.org/10.1007/BF00504108

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  • DOI: https://doi.org/10.1007/BF00504108

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