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Pyrroles from ketoximes and acetylene. 41. Some reactions of 1-vinyl-2-(2-furyl)- and-(2-thienyl)pyrroles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

We have studied the reaction of 1-vinyl-2-(2-furyl)- and -(2-thienyl)pyrroles with trifluoroacetic anhydride, with hydrogen in the presence of catalysts (Raney nickel, palladium black, palladous chloride), with propargyl alcohol in electrophilic conditions [catalysis by perfluorobutyric acid in the system azoisobutyrodinitrile (AIBN)-CCl4), and with alkane thiols with AIBN initiation. The products are novel substituted hetarylpyrroles.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Irkutsk

    S. E. Korostova, R. N. Nesterenko, A. I. Mikhaleva, S. G. Shevchenko, G. A. Kalabin & R. I. Polovnikova

Authors
  1. S. E. Korostova
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  2. R. N. Nesterenko
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  3. A. I. Mikhaleva
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  4. S. G. Shevchenko
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  5. G. A. Kalabin
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  6. R. I. Polovnikova
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Additional information

See [1] for Communication 40.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 337–342, March, 1991.

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Korostova, S.E., Nesterenko, R.N., Mikhaleva, A.I. et al. Pyrroles from ketoximes and acetylene. 41. Some reactions of 1-vinyl-2-(2-furyl)- and-(2-thienyl)pyrroles. Chem Heterocycl Compd 27, 273–278 (1991). https://doi.org/10.1007/BF00474228

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  • DOI: https://doi.org/10.1007/BF00474228

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