Abstract
Silicate inclusions in 17 iron meteorites have been analyzed by the electron microprobe and classified, according to their phase assemblages, compositions, and textures, into three major types: Odessa, Copiapo, and Weekeroo Station, and three miscellaneous types: Enon, Kendall County, and Netschaëvo. Phase compositions in both Odessa- and Copiapo-type inclusions are very similar, but the two types are different in texture and constituent phases. Weekeroo Station-type inclusions are very different in every respect from other inclusions.
For Odessa- and Copiapo-type inclusions, the distribution coefficients of Fe2+ and Mg in coexisting orthopyroxene and clinopyroxene indicate equilibration temperatures of ∼1,000° C, and the Ca/(Ca+Mg) ratios indicate temperatures of 900° C to 1,000° C. Equilibration temperatures determined for chromite-olivine pairs have a higher range of 1,154° C to 1,335° C. Minor element distributions among coexisting ferromagnesian silicates in these inclusions follow consistent patterns and are constant for any given sample, suggesting equilibrium assemblages. Major and minor element distributions for Weekeroo Station inclusions are anomalous, indicating nonequilibrium.
Compositional data, the fragmentary shapes of many inclusions, the highly differentiated characteristic of two types of inclusions, the apparent disequilibrium between kamacite in inclusions and kamacite of the iron host, and the relict chondrules found in Netschaëvo suggest that many of the inclusions did not form cogenetically with the iron host, but represent pre-existing stony material that was taken up by an iron melt, probably not in the core of the parent body (or bodies).
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References
Anders, E.: Origin, age and composition of meteorites. Space Sci. Rev. 3, 583–714 (1964).
Aoki, K., Kushiro, I.: Some clinopyroxenes from ultramafic inclusions in Dreiser Weiher, Eifel. Contr. Mineral and Petrol. 18, 326–337 (1968).
Bartholome, P.: Co-existing pyroxenes in igneous and metamorphic rocks. Geol. Mag. 98, 346–348 (1961).
Bence, A. E., Burnett, D. S.: Chemistry and mineralogy of the silicates and metal of the Kodaikanal meteorite. Geochim. Cosmochim. acta 33, 375–385 (1969).
Berwerth, F.: Das Meteoreisen von Kodaikanal und seine Silikatausscheidungen. Tschermaks Mineral. Petrog. Mitt. 25, 179–197 (1906).
Bogard, D., Burnett, D., Eberhardt, P., Wasserburg, G. J.: 40Ar-40K ages of silicate inclusions in iron meteorites. Earth and Planet. Sci. Letters 3, 275–283 (1968).
Bowen, N., Schairer, J.: The system MgO-FeO-SiO2. Am. J. Sci. 29, 151–217 (1935).
Boyd, F. R., Schairer, J. F.: The system MgSiO3-CaMgSi2O6. J. Petrol.5, 275–309 (1964).
Bunch, T. E., Fuchs, L. H.: Yagiite, a sodium-magnesium analogue of osumilite. Am. Mineralogist 54, 14–19 (1969).
—, Keil, K., Snetsinger, K. G.: Chromite composition in relation to chemistry and texture of ordinary chondrites. Geochim. Cosmochim. Acta 31, 1569–1582 (1967).
—, Olsen, E.: Potassium feldspar in Weekeroo Station, Kodaikanal, and Colomera iron meteorites. Science 160, 1223–1225 (1968).
Burnett, D. S., Wasserburg, G. J.: Evidence for the formation of iron meteorite at 3.8×109 years. Earth and Planet. Sci. Letters 2, 137–147 (1967a).
— —: 87Rb-87 Sr ages of silicate inclusions in iron meteorites. Earth and Planet. Sci. Letters 2, 397 (1967b).
Buseck, P. R., Keil, K.: Meteoritic rutile. Am. Mineralogist 51, 1506–1515 (1966).
Carstens, H.: Note on the distribution of some minor elements in coexisting ortho- and clinopyroxenes. Norsk. Geol. Tiddsk. 38, 257–260 (1958).
Cohen, E.: Meteoreisen-Studien XI. Ann. Naturhist. Hofmus. Wien 15, 382 (1900).
—: Meteoritenkunde, H. III, 419 pp. Stuttgart: I. E. Schweizerbart 1905.
Davis, B. T. C., Boyd, F. R.: The join Mg2Si2O6-CaMgSi2O6 at 30 kb pressure and its application to pyroxenes from kimberlites. J. Geophys. Res. 71, 3567–3576 (1966).
Deer, W. A., Howie, R. A., Zussman, J.: Rock forming minerals, vol.2: Chain silicates, 4th ed. London: Longmans, Green & Co. Ltd. 1963.
Duncumb, P., Shields, P. K.: Effect of critical excitation potential on the absorption correction in X-ray micro-analysis. Proc. Symp. on Electron Microprobe, Washington, D.S., 1964. (T. D. McKinley, K. F. J. Heinrich, and D. B. Wittry, editors), p. 284–295. New York: John Wiley 1966.
El Goresy, A.: Mineralbestand und Strukturen der Graphit- und Sulphideinschlüsse in Eisenmeteoriten. Geochim. Cosmochim. Acta 29, 1131–1151 (1965).
- Quantitative electron microprobe analyses of K-feldspar grains from the Odessa iron meteorite. Abstract, 30th Meeting of the Meteoritical Society, October 25–27 (1967).
Fricker, P. E., Goldstein, J. I., Summers, A. L.: Cooling rates and thermal histories of iron and stony-iron meteorites. Geochim. Cosmochim. Acta (In press).
Fuchs, L.: Occurrence of whitlockite in chondritic meteorites. Science 137, 425–426 (1962).
—: The phosphate mineralogy of meteorites. Symposium on Meteorite Research (P. M. Millman, ed.), p. 319–331. Dordrecht, Holland: D. Reidel, Publ. Co. 1969.
—, Olsen, E., Henderson, E.: On the occurrence of brianite and panethite, two new phosphate minerals from the Dayton meteorite. Geochim. Cosmochim. Acta 31, 1711–19 (1967).
Goldstein, J., Short, J.: Cooling rates of 27 iron and stony-iron meteorites. Preprint X-641-66-289, Goddard Space Flight Center, Greenbelt, Md. (1966).
Grover, J., Orville, P.: The partitioning of cations between coexisting single-and multi-site phases with application to the assemblages: orthopyroxene-clinopyroxene and orthopyroxene-olivine. Geochim. Cosmochim. Acta 33, 205–226 (1969).
Heinrich, K. F. J.: X-ray absorption uncertainty. Proc. Symp. on Electron Microprobe, Washington, D. C., 1964 (T. D. McKinley, K. F. J. Heinrich, and D. B. Wittry, editors), p. 296–377. New York: John Wiley 1966.
Henderson, E. P., Perry, S. H.: The Linwood (Nebraska) meteorite. U. S. Nat. Museum Proceed. 99, 357–360 (1949).
Hodge-Smith, T.: The Weekeroo Station meteorite: A siderite from South Australia. Rec. Austr. Mus. 17, 312–313 (1932).
Jackson, E. D.: Chemical variation in coexisting chromite and olivine in chromite zones of the Stillwater Complex. (In press).
Keil, K.: Mineralogical modal analysis with the electron microprobe X-ray analyzer. Am. Mineralogist 50, 2089–2092 (1965).
—: Mineralogical and chemical relationships among enstatite chondrites. J. Geophys. Res. 73, 6945–6976 (1968).
—: Meteorite composition. Handbook of Geochemistry (K. H. Wedepohl, editor). p. 78–115. Berlin-Heidelberg-New York: Springer 1969.
Kretz, R.: Some applications of thermo-dynamics to coexisting minerals of variable composition. Examples: orthopyroxene-clinopyroxene and orthopyroxene-garnet. J. Geol. 69, 361–387 (1961).
—: Distribution of magnesium and iron between orthopyroxene and calcic pyroxene in natural mineral assemblages. J. Geol. 71, 773–785 (1963).
Marshall, R. R.: Devitrification of natural glass. Bull. Geol. Soc. Am. 72, 1493–1520 (1961).
—, Keil, K.: Polymineralic inclusions in the Odessa iron meteorite. Icarus 4, 461–479 (1965).
Mason, B.: The Woodbine meteorite, with notes on silicates in iron meteorites. Mineral. Mag. 36, 120–127 (1967).
McCallum, I. S.: Equilibrium relationships among the coexisting minerals in the Stillwater Complex, Montana. Ph. D. Dissertation, Univ. of Chicago (1968).
Merrill, G. P.: Quartz in meteoric stones. Am. Mineralogist 9, 112–113 (1924).
Mueller, R. F.: Compositional characteristics of equilibrium relations in mineral assemblages of a metamorphosed iron formation. Am. J. Sci. 258, 449–497 (1960).
—: Analysis of relations among Mg, Fe and Mn in certain metamorphic minerals. Geochim. Cosmochim. Acta 25, 267–296 (1961).
—: Phase equilibria and the crystallization of chondritic meteorites. Geochim. Cosmochim. Acta 28, 189–207 (1964).
Nafziger, R. H., Muan, A.: Equilibrium phase compositions and thermodynamic properties of olivines and pyroxenes in the system MgO-“FeO”-SiO2. Am. Mineralogist 52, 1364–85 (1967).
Nixon, P. H., Knorring, O. v., Rooke, J. M.: Kimberlites and associated inclusions of Basutoland: A mineralogical and chemical study. Am. Mineralogist 48, 1090–1132 (1963).
Olsen, E.: Amphibole: first occurrence in meteorite. Science 156, 61–62 (1967).
- Jarosowich, E.: The bulk composition of silicate inclusions in the Weekeroo Station iron meteorite. (In preparation.)
—, Mueller, R. F.: Silicates in some iron meteorites. Nature 201, 596–597 (1963).
— —: Stability of orthopyroxenes with respect to pressure, temperature, and composition. J. Geol. 74, 620–625 (1966).
Park, F. R., Bunch, T. E., Massalski, T. B.: A study of the silicate inclusions and other phases in the Campo del Cielo meteorite. Geochim. Cosmochim. Acta 30, 399–414 (1966).
Philibert, J. A.: A method for calculating the absorption correction in electron probe microanalysis. Proc. Third Internat. Symp. on X-ray optics and X-ray microanalysis, Stanford, 1962 (H. H. Pattee, V. E. Cosslett, and A. Engstrom, editors), p. 379–392. New York: Academic Press 1963.
Prior, G.: On the mesosiderite-grahamite group of meteorites. Mineral. Mag. 18, 151–172 (1918).
Ramberg, H., de Vore, G. W.: The distribution of Fe2+ and Mg2+ in coexisting olivines and pyroxenes. J. Geol. 59, 193–210 (1951).
Ramdohr, P.: Chromite and chromite chondrules in meteorites I. Geochim. Cosmochim. Acta 31, 1961–1967 (1967).
Ringwood, A.: Chemical and genetic relationships among meteorites. Geochim. Cosmochim. Acta 24, 159–197 (1961).
Saxena, S. K.: Crystal-chemical aspects of distribution of elements among certain coexisting rock-forming silicates. Neues Jahrb. Mineral. Abhandl. 108, 292–323 (1968).
Schmus, Van, R., Koffman, D.: Equilibration temperatures of iron and magnesium in chondritic meteorites. Science 155, 1009–1011 (1967).
Taylor, H. P., Jr.: Oxygen isotope geochemistry of igneous rocks. Contr. Mineral and Petrol. 19, 1–71 (1968).
Thompson, J. B.: Role of aluminium in rock forming silicates. Bull. Geol. Soc. Am. 58, 1232 (1947).
Urey, H. C., Craig, H.: The composition of the stone meteorites and the origin of the meteorites. Geochim. Cosmochim. Acta 4, 38–82 (1953).
—: Chemical evidence relative to the origin of the solar system. Monthly Notices Roy. Astron. Soc. 131, 199–233 (1966).
Wasserburg, G.J., Burnett, D.S., Frondel, C.: Strontium-rubidium age of an Iron meteorite. Science 150, 1814 (1965).
—, Sanz, H. G., Bence, A. E.: Potassium feldspar phenocrysts in the surface of Colomera, an iron meteorite. Science 161, 684–687 (1968).
White, R. W.: Ultramafic inclusions in basaltic rocks from Hawaii. Contr. Mineral. and Petrol. 12, 246–314 (1966).
Wittry, D. B.: Methods of quantitative electron probe analysis. Proc. Twelfth Ann. Conf. on Applied X-ray Analysis, Denver, 1963 (W. H. Mueller, G. Mallett, and M. Fay, editors), vol. 7, p. 395–418. New York: Plenum Press 1964.
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Bunch, T.E., Keil, K. & Olsen, E. Mineralogy and petrology of silicate inclusions in iron meteorites. Contr. Mineral. and Petrol. 25, 297–340 (1970). https://doi.org/10.1007/BF00399290
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DOI: https://doi.org/10.1007/BF00399290