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N-alkyl-3-vinylpyridinium salts: homopolymerization of the hexadecyl derivative and behaviour study of the polymer in aqueous media

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We report on the preparation and the characterization of R-alkylated quaternary salts (with RCCH3, C12H25, C16H33, X=Br-) derived from 3-vinylpyridine (3-VP). Our first attempts on free radical polymerization of 1-hexadecyl-3-vinylpyridinium bromide in benzene solution were described. The viscosimetric behaviour and binding of dye (Methyl Orange) to this homopolymer in aqueous media were interpreted as the formation of compact coils resulting in the presence of hydrophobic microdomains.

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Authors and Affiliations

  1. Laboratoire de Chimie-Physique Macromoléculaire, CNRS-URA-494, ENSIC, INPL, 1 Rue Grandville, BP 451, F-54001, Nancy Cedex, France

    Abdesselam Benjelloun, Christine Damas, Alain Brembilla & Pierre Lochon

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  1. Abdesselam Benjelloun
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  2. Christine Damas
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  3. Alain Brembilla
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  4. Pierre Lochon
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Benjelloun, A., Damas, C., Brembilla, A. et al. N-alkyl-3-vinylpyridinium salts: homopolymerization of the hexadecyl derivative and behaviour study of the polymer in aqueous media. Polymer Bulletin 33, 513–520 (1994). https://doi.org/10.1007/BF00296158

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  • DOI: https://doi.org/10.1007/BF00296158

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