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Miscibility of poly(p-vinyl phenol) with polymethacrylates

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Summary

Poly(p-vinyl phenol) is miscible with poly(methyl methacrylate), poly(ethyl methacrylate), poly(n-propyl methacrylate), poly(isopropyl methacrylate), and poly(tetrahydrofurfuryl methacrylate), but is immiscible with poly(n-butyl methacrylate). Except for poly(p-vinyl phenol)/ poly(methyl methacrylate) blends, the other miscible blends show pronounced positive deviations in their glass transition temperatures. The Tg-composition curves of the five miscible blend systems can be described by the Gordon-Taylor and the Kwei equations.

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Authors and Affiliations

  1. Department of Chemistry, National University of Singapore, 0511, Singapore, Republic of Singapore

    S. H. Goh & K. S. Siow

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  1. S. H. Goh
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  2. K. S. Siow
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Goh, S.H., Siow, K.S. Miscibility of poly(p-vinyl phenol) with polymethacrylates. Polymer Bulletin 17, 453–458 (1987). https://doi.org/10.1007/BF00255618

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