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Origin of calcium in aerosols over the western North Pacific

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Abstract

Weekly aerosol samples were collected from March 1981 to June 1983 at the six stations in the western North Pacific region and analyzed for Ca and Na. By coupling data with those previously reported for Al (Tsunogai et al., 1985), the following results and conclusion have been obtained. There was a positive correlation between the atmospheric concentration of Al and the concentration of nonsea salt Ca (nssCa). The nssCa/Al ratios from the six stations, however, considerably varied (from 0.84±0.36 to 3.00±1.91), and the ratios were usally larger than those of the crustal average or of usual soil in Japan. The Ca/Al ratios of Asian desert soil and loess vary from 0.52 to 1.29, which are similar to the nssCa/Al ratios of aerosols in the surface air over the western North Pacific region except at Onna, Okinawa. The exception may be due to a local effect of coral. These results suggest that a large part of nonsea salt Ca in the surface air over the western North Pacific is derived from arid regions in Asia and that the nssCa/Al ratio in aerosol varies with that of the source material.

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References

  • Bruland, K. W., 1983, Trace elements in sea-water, in J. P., Riley and R., Chester (eds.), Chemical Oceanography vol. 8, Academic Press, London, pp. 157–215.

    Google Scholar 

  • Darzi, M. and Winchester, J. W., 1982, Aerosol characteristics at Mauna Loa observatory, Hawaii, after east Asian dust storm episodes, J. Geophys. Res. 87, 1251–1258.

    Google Scholar 

  • Duce, R. A., Unni, C. K., Ray, B. J., Prospero, J. M., and Merrill, J. T., 1980, Long-range atmospheric transport of soil dust from Asia to the tropical North Pacific: Temporal variability, Science 209, 1522–1524.

    Google Scholar 

  • Funabiki, S., 1958, Soil Science, Asakurashoten, Tokyo, pp. 73–77 (in Japanese).

    Google Scholar 

  • Griffin, J. J., Windom, H., and Goldberg, E. D., 1968, The distribution of clay minerals in the world ocean, Deep-Sea Res. 15, 433–459.

    Google Scholar 

  • Hirose, K. and Sugimura, Y., 1984, Excess 228Th in the airborne dust: an indicator of continental dust from the East Asian deserts, Earth Planet. Sci. Lett. 70, 110–114.

    Google Scholar 

  • Hoffman, E. J. and Duce, R. A., 1977, Alkali and alkaline earth metal chemistry of marine aerosols generated in the laboratory with natural seawaters, Atmos. Environ. 11, 367–372.

    Google Scholar 

  • Hoffman, E. J., Hoffman, G. L., Fletcher, I. S., and Duce, R. A., 1977, Further consideration of alkali and alkaline earth geochemistry of marine aerosols: Results of a study of marine aerosols collected on Bermuda, Atmos. Environ. 11, 373–377.

    Google Scholar 

  • Ichikuni, M., 1978, Calcite as a source of exess calcium in rainwater, J. Geophys. Res. 83, 6249–6252.

    Google Scholar 

  • Ishizaka, Y., 1972, On materials of solid particles contained in snow and rain water: Part 1, J. Meteor. Soc. Japan 50, 362–375.

    Google Scholar 

  • Ishizaka, Y., 1973, On materials of solid particles contained in snow and rain water: Part 2, J. Meteor. Soc. Japan 51, 325–333.

    Google Scholar 

  • Ishizaka, Y., Ono, A., and Kadowaki, S., 1981, Size distribution and mineral composition of yellow sand in the air over Japan and its main origins, Tenki 28, 651–665 (in Japanese).

    Google Scholar 

  • Iwasaka, Y., Minoura, H., and Nagaya, K., 1983, The transport and spacial scale of Asian dust-storm clouds: a case study of the dust-storm event of April 1979, Tellus 35B, 189–196.

    Google Scholar 

  • Li, Y. H., Teraoka, H., Yang, T. S., and Chen, J. S., 1984, The elemental composition of suspended particles from the Yellow and Yangtze Rivers, Geochim. Cosmochim. Acta 48, 1561–1564.

    Google Scholar 

  • Lisitzin, A. P., 1978, Process of Oceanic Sedimentation, Nauka, Moscow, pp. 58–60 (in Russian).

    Google Scholar 

  • Loÿe-Pilot, M. D., Martin, J. M., and Morelli, J., 1986, Influence of Saharan dust on the rain acidity and atmospheric input to the Mediterranean, Nature 321, 427–428.

    Google Scholar 

  • Maenhaut, W., Darzi, M., and Winchester, J. W., 1981, Seawater and nonseawater aerosol components in the marine atmosphere of Samoa, J. Geophys. Res. 86, 3187–3193.

    Google Scholar 

  • Maenhaut, W., Raemdonck, H., Selen, A., Van, Grieken, R., and Winchester, J. W., 1983, Characterization of the atmospheric aerosol over the eastern equatorial Pacific, J. Geophys. Res. 88, 5353–5364.

    Google Scholar 

  • Miyake, Y., Sugiura, Y. and Katsuragi, Y., 1956, Radioactive fallout at Asahikawa, Hokkaido in April, 1955, J. Meteor. Soc. Japan 34, 226–230 (in Japanese).

    Google Scholar 

  • Noriki, S., Nakanishi, K., Fukawa, T., Uematsu, M., Uchida, T. and Tsunogai, S., 1980, Use of sealed teflon vessel for the decomposition followed by the determination of chemical constituents of various marine samples, Bull. Fac. Fish. Hokkaido Univ. 31, 354–361 (in Japanese).

    Google Scholar 

  • Nozaki, Y., Thomson, J., and Turekian, K. K., 1976, The distribution of 210Pb and 210Po in the surface waters of the Pacific Ocean, Earth Planet. Sci. Lett. 32, 304–312.

    Google Scholar 

  • Parrington, J. R., Zoller, W. H., and Aras, N. K., 1983, Asian dust: Seasonal transport to the Hawaiian Islands, Science 220, 195–197.

    Google Scholar 

  • Rex, R. V. and Goldberg, E. D., 1958, Quartz contents of pelagic sediments of the Pacific Ocean, Tellus 10, 153–159.

    Google Scholar 

  • Sugawara, K., Oana, S., and Koyama, T., 1949, Separation of the components of atmospheric salt and their distribution, Bull. Chem. Soc. Jap. 22, 47–52.

    Google Scholar 

  • Suzuki, T. and Tsunogai, S., 1988, Daily variation of aerosols of marine and continental origin in the surface air over a small island, Okushiri in the Japan Sea, Tellus 40B, 42–49.

    Google Scholar 

  • Taylor, S. R., 1964, Abundance of chemical elements in the continental crust: a new table, Geochim. Cosmochim. Acta 28, 1273–1285.

    Google Scholar 

  • Tsunogai, S. and Nozaki, Y., 1971, Lead-210 and polonium-210 in the surface water of the Pacific, Geochem. J. 5, 165–173.

    Google Scholar 

  • Tsunogai, S., Saito, O., Yamada, K., and Nakaya, S., 1972, Chemical composition of oceanic aerosol, J. Geophys. Res. 77, 5283–5292.

    Google Scholar 

  • Tsunogai, S., 1975, Sea salt particles transported to the land, Tellus 27, 51–58.

    Google Scholar 

  • Tsunogai, S. and Shinagawa, T., 1977, Chemical components transported by the winter monsoon, Chikyukagaku 11, 1–8 (in Japanese).

    Google Scholar 

  • Tsunogai, S. and Kondo, T., 1982, Sporadic transport and deposition of continental aerosols to the Pacific Ocean, J. Geophys. Res. 87, 8870–8874.

    Google Scholar 

  • Tsunogai, S., Suzuki, T., Kurata, T., and Uematsu, M., 1985, Seasonal and areal variation of continental aerosol in the surface air over the western North Pacific region, J. Oceanogr. Soc. Japan 41, 427–434.

    Google Scholar 

  • Uematsu, M., Duce, R. A., Prospero, J. M., Chen, L., Merrill, J. T., and McDonald, R. L., 1983, Transport of mineral aerosol from Asia over the North Pacific Ocean, J. Geophys. Res. 88, 5343–5352.

    Google Scholar 

  • Uematsu, M., Duce, R. A., Nakaya, S., and Tsunogai, S., 1985a, Short-term temporal variability of eolian particles in surface waters of the northwestern North Pacific. J. Geophys. Res. 90, 1167–1172.

    Google Scholar 

  • Uematsu, M., Duce, R. A., and Prospero, J. M., 1985b, Deposition of atmospheric mineral particles in the North Pacific Ocean, J. Atmos. Chem. 3, 123–138.

    Google Scholar 

  • Winchester, J. W. and Bi, Mu-tian, 1984, Fine and coarse aerosol composition in an urban setting: A case study in Beijing, China, Atmos. Environ. 18, 1399–1409.

    Google Scholar 

  • Yasuda, K. and Hasegawa, N., 1972, Atomic Absorption Spectrophotometry, Kodansha, Tokyo, pp. 135–138 (in Japanese).

    Google Scholar 

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Suzuki, T., Tsunogai, S. Origin of calcium in aerosols over the western North Pacific. J Atmos Chem 6, 363–374 (1988). https://doi.org/10.1007/BF00051597

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