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Spin Transition in BiCoO3 Correlated with Large Polar Distortion and Its Applications

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Spin-Crossover Cobaltite

Part of the book series: Springer Series in Materials Science ((SSMATERIALS,volume 305))

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Abstract

Perovskite oxide BiCoO3 belongs to the class of compounds that show the spin transition of the Co ion. The spin state of Co3+ in BiCoO3 is closely correlated with its crystal structure. The application of high pressure induces structural transition accompanied by spin transition. This chapter describes the correlation between the large structural distortion and the spin state of Co3+ in BiCoO3. In addition, negative thermal expansion, which is observed in the BiCoO3-BaTiO3 system, and polarization rotation in the BiCo1−xFexO3 solid solution system are introduced.

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Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Science and Engineering, Kindai University, Higashiosaka, Osaka, 577-8502, Japan

    Kengo Oka

  2. Laboratory for Materials and Structures, Tokyo Institute of Technology, Yokohama, 226-8503, Japan

    Masaki Azuma

Authors
  1. Kengo Oka
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  2. Masaki Azuma
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Correspondence to Kengo Oka .

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Editors and Affiliations

  1. Department of Chemistry, Tokyo Institute of Technology, Tokyo, Japan

    Yoichi Okimoto

  2. Department of Applied Physics, Tokyo University of Science, Tokyo, Japan

    Tomohiko Saitoh

  3. Department of Physics, Tokyo Medical University, Tokyo, Japan

    Yoshihiko Kobayashi

  4. (Deceased) Department of Physics, Tohoku University, Sendai, Japan

    Sumio Ishihara

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Oka, K., Azuma, M. (2021). Spin Transition in BiCoO3 Correlated with Large Polar Distortion and Its Applications. In: Okimoto, Y., Saitoh, T., Kobayashi, Y., Ishihara, S. (eds) Spin-Crossover Cobaltite. Springer Series in Materials Science, vol 305. Springer, Singapore. https://doi.org/10.1007/978-981-15-7929-5_6

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