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Natural Compounds for the Stabilization and Coloration of Polypropylene

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Physics and Techniques of Ceramic and Polymeric Materials (CMC 2018)

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Abstract

The effects of two new natural substances (celery and Lycium chinense fruits) on the stability of polypropylene (PP) were investigated. Thermogravimetric analysis (TGA) and oxidation induction time (OIT) were conducted to investigate the thermal and thermo-oxidative stability. Melt flow rate (MFR) was tested for the processing stability. Results showed that the addition of natural substances did not change the thermal degradation behavior of PP, but greatly enhanced the thermal and thermo-oxidative stability. The temperature at 5 wt% loss (T5%) of PP-L1.2 sample was 13 °C higher than pure PP. The OIT value of PP-L1.2 sample was about 1.8 times as many as that of pure PP after the first extrusion. Moreover, the change of MFR for PP-L1.2 sample between first and fifth extrusions was smaller than PP. As for PP-C1.2 sample, the T5% and OIT were both increased compared with PP. The change of MFR was also smaller than PP. All results confirm that celery and Lycium chinense fruits can be used as antioxidants and colorants for PP.

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References

  1. C.C. Hsu, P.H. Geil, H. Miyaji, K. Asai, Structure and properties of polypropylene crystallized from the glassy state. Polym. Sci. Part B Polym. Phys. 24, 2379–2401 (1986)

    Article  CAS  Google Scholar 

  2. S. Costanzi, R. Farris, D. Girelli, New high performance phosphites. Polym. Degrad. Stab. 73(3), 425–430 (2001)

    Article  CAS  Google Scholar 

  3. B. Xue, K. Ogata, A. Toyota, Synthesis of polymeric antioxidants based on ring-opening metathesis polymerization (ROMP) and their antioxidant ability for preventing polypropylene (PP) from thermal oxidation degradation. Polym. Degrad. Stab. 93, 347–352 (2008)

    Article  CAS  Google Scholar 

  4. I. Kriston, O.M. Ágnes, G. Nagy, P. Staniek, E. Fӧldes, B. Pukánszky, Melt stabilisation of Phillips type polyethylene, part I: The role of phenolic and phosphorous antioxidants. Polym. Degrad. Stab. 94(4), 719–729 (2009)

    Article  CAS  Google Scholar 

  5. B. Kirschweng, D. Tátraaljai, E. Fӧldes, B. Pukánszky, Natural antioxidants as stabilizers for polymers. Polym. Degrad. Stab. 145, 25–40 (2017)

    Article  CAS  Google Scholar 

  6. D. Brocca, E. Arvin, H. Mosbæk, Identification of organic compounds migrating from polyethylene pipelines into drinking water. Water Res. 36, 3675–3680 (2002)

    Article  CAS  Google Scholar 

  7. K.A. Iyer, L.H. Zhang, M. Torkelson, Direct use of natural antioxidant-rich agro-wastes as thermal stabilizer for polymer: Processing and recycling. ACS Sustainable Chem. Eng. 4, 881–889 (2016)

    Article  CAS  Google Scholar 

  8. D. Tátraaljai, L. Major, E. Fӧldes, B. Béla Pukánszky, B. Pukánszky, Study of the effect of natural antioxidants in polyethylene: Performance of β-carotene. Polym. Degrad. Stab. 102, 33–40 (2014)

    Article  Google Scholar 

  9. D. Tátraaljai, B. Kirschweng, J. Kovacs, E. Fӧldes, B. Pukánszky, Processing stabilisation of PE with a natural antioxidant, curcumin. Eur. Polym. J. 49(6), 1196–1203 (2013)

    Article  Google Scholar 

  10. B. Kirschweng, D. Tátraaljai, E. Fӧldes, B. Pukánszky, Efficiency of curcumin, a natural antioxidant, in the processing stabilization of PE: concentration effects. Polym. Degrad. Stab. 118, 17–23 (2015)

    Article  CAS  Google Scholar 

  11. D. Tátraaljai, E. Fӧldes, B. Pukánszky, Efficient melt stabilization of poly-ethylene with quercetin, a flavonoid type natural antioxidant. Polym. Degrad. Stab. 102, 41–48 (2014)

    Article  Google Scholar 

  12. B. Kirschweng, K. Bencze, M. Sárközi, B. Hégely, G. Samu, J. Hári, D. Tátraaljai, E. Földes, M. Kállay, B. Pukánszky, Melt stabilization of polyethylene with dihydromyricetin, a natural antioxidant. Polym. Degrad. Stab. 133, 192–200 (2016)

    Article  CAS  Google Scholar 

  13. M. Messori, A comparative study of different winemaking by-products derived additives on oxidation stability, mechanical and thermal proprieties of polypropylene. Polym. Degrad. Stab. 149, 9–18 (2018)

    Article  Google Scholar 

  14. M.L. Xin, Y.J. Ma, W.H. Lin, K. Xu, M.C. Chen, Use of dihydromyricetin as antioxidant for polypropylene Stabilization. J. Therm. Anal. Calorim. 120, 1741–1747 (2015)

    Article  CAS  Google Scholar 

  15. R.A. Momin, M.G. Nair, Antioxidant, cyclooxygenase and topoisomerse inhibitory compounds from Apium graveolens Linn. seeds. Phytomedicine 9(4), 312–318 (2002)

    Article  CAS  Google Scholar 

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Correspondence to Qing Yu .

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Gao, H. et al. (2019). Natural Compounds for the Stabilization and Coloration of Polypropylene. In: Han, Y. (eds) Physics and Techniques of Ceramic and Polymeric Materials. CMC 2018. Springer Proceedings in Physics, vol 216. Springer, Singapore. https://doi.org/10.1007/978-981-13-5947-7_8

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  • DOI: https://doi.org/10.1007/978-981-13-5947-7_8

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