Abstract
The value of an industrial product is generally determined by: a) cost to manufacture it, b) safety of process and/or product, c) environmental acceptance and compatibility. Regarding the chemical industry, the selectivity of a reaction is often the key feature in obtaining the above targets. This implies that search for selectivity provides a great challenge to the chemical industry necessitating substantial research and development efforts. In aiming at selectivity, catalysis plays an important role. In the last decades, homogeneous transition metal based catalysts have emerged as especially promising in obtaining selectivity.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
O’Connor, C. and Wilkinson, G. J. Chem. Soc. 1968, A., 2668.
Keim, W.; Chung, H. J. Org. Chem. 1972, 37, 947.
Bogdanovic, B. Adv. Organomet. Chem. 1979, 77, 105–137.
Keim, W.; Behr, A.; Kraus, G. J. Organomet. Chem. 1983, 251, 377.
Keim, W. Angew. Chem. Int. Ed. Engl. 1990, 29, 235–244.
Parshall, G.W. Homogeneous Catalysis, Wiley-Interscience, New York 1980, 235–244.
Bosnich, B. Topics in Inorganic and Organometallic Stereochemistry, Vol. 12, Geoffroy, G.L. Ed., John Wiley 1986, p 119.
Kaminsky, W. Catalytic Polymerization of Olefins, Keii, T.; Soga, K. Ed., Elsevier Amsterdam, 1986, p 293.
Keim, W.; Koehnes, A.; Roethel, T.; Enders, D. J. Org. Chem. 1990, 382, 295.
Enders, D.; Kipphardt, H. Nachr. Chem. Tec. Lab. 1985, 33, Nr 10-992.
Merck Schuchard, Frankfurter Str. 250, D-6100 Darmstadt (FRG).
Keim, W.; Koehnes, A.; Roethel, T. J. Organic Chem. (in preparation).
Groves, J.T.; Neumann, R. J. Am. Chem. Soc. 1989, 111, 2900.
Keim, W. J. Molec. Cat. 1989, 52, 19.
Mehlborn, A. unpublished (on going thesis) RWTH Aachen.
Keim, W. Chem.-Ing.-Tech. 1984, 56, 850
Freitas, E.R.; Gum, C.R. Chem. Eng. Prog. 1979, 75, 73
Behr, A.; Keim, W. Arabian J. Sci. Eng. 1984, 10, 377
Keim, W.; Kowaldt, F.H.; Goddard, R.; Krüger, C. Angew. Chem. 1978, 90, 493;
Angew Chem. Int. Ed. Engl. 1978, 17, 466
Keim, W.; Behr, A.; Gruber, B.; Hoffmann, B.; Kowaldt, F.H.; Kürschner, U.; Limbäcker, B.; Sistig, F.P. Organometallics 1986, 5, 2356.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1991 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Keim, W. (1991). Industrial Aspects of Selectivity Applying Homogeneous Catalysis. In: Noels, A.F., Graziani, M., Hubert, A.J. (eds) Metal Promoted Selectivity in Organic Synthesis. Catalysis by Metal Complexes, vol 12. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3408-8_1
Download citation
DOI: https://doi.org/10.1007/978-94-011-3408-8_1
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-5508-6
Online ISBN: 978-94-011-3408-8
eBook Packages: Springer Book Archive