Skip to main content

Industrial Aspects of Selectivity Applying Homogeneous Catalysis

  • Chapter
Metal Promoted Selectivity in Organic Synthesis

Part of the book series: Catalysis by Metal Complexes ((CMCO,volume 12))

Abstract

The value of an industrial product is generally determined by: a) cost to manufacture it, b) safety of process and/or product, c) environmental acceptance and compatibility. Regarding the chemical industry, the selectivity of a reaction is often the key feature in obtaining the above targets. This implies that search for selectivity provides a great challenge to the chemical industry necessitating substantial research and development efforts. In aiming at selectivity, catalysis plays an important role. In the last decades, homogeneous transition metal based catalysts have emerged as especially promising in obtaining selectivity.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. O’Connor, C. and Wilkinson, G. J. Chem. Soc. 1968, A., 2668.

    Google Scholar 

  2. Keim, W.; Chung, H. J. Org. Chem. 1972, 37, 947.

    Article  CAS  Google Scholar 

  3. Bogdanovic, B. Adv. Organomet. Chem. 1979, 77, 105–137.

    Article  Google Scholar 

  4. Keim, W.; Behr, A.; Kraus, G. J. Organomet. Chem. 1983, 251, 377.

    Article  CAS  Google Scholar 

  5. Keim, W. Angew. Chem. Int. Ed. Engl. 1990, 29, 235–244.

    Article  Google Scholar 

  6. Parshall, G.W. Homogeneous Catalysis, Wiley-Interscience, New York 1980, 235–244.

    Google Scholar 

  7. Bosnich, B. Topics in Inorganic and Organometallic Stereochemistry, Vol. 12, Geoffroy, G.L. Ed., John Wiley 1986, p 119.

    Google Scholar 

  8. Kaminsky, W. Catalytic Polymerization of Olefins, Keii, T.; Soga, K. Ed., Elsevier Amsterdam, 1986, p 293.

    Google Scholar 

  9. Keim, W.; Koehnes, A.; Roethel, T.; Enders, D. J. Org. Chem. 1990, 382, 295.

    Article  CAS  Google Scholar 

  10. Enders, D.; Kipphardt, H. Nachr. Chem. Tec. Lab. 1985, 33, Nr 10-992.

    Google Scholar 

  11. Merck Schuchard, Frankfurter Str. 250, D-6100 Darmstadt (FRG).

    Google Scholar 

  12. Keim, W.; Koehnes, A.; Roethel, T. J. Organic Chem. (in preparation).

    Google Scholar 

  13. Groves, J.T.; Neumann, R. J. Am. Chem. Soc. 1989, 111, 2900.

    Article  CAS  Google Scholar 

  14. Keim, W. J. Molec. Cat. 1989, 52, 19.

    Article  CAS  Google Scholar 

  15. Mehlborn, A. unpublished (on going thesis) RWTH Aachen.

    Google Scholar 

  16. Keim, W. Chem.-Ing.-Tech. 1984, 56, 850

    Article  CAS  Google Scholar 

  17. Freitas, E.R.; Gum, C.R. Chem. Eng. Prog. 1979, 75, 73

    CAS  Google Scholar 

  18. Behr, A.; Keim, W. Arabian J. Sci. Eng. 1984, 10, 377

    Google Scholar 

  19. Keim, W.; Kowaldt, F.H.; Goddard, R.; Krüger, C. Angew. Chem. 1978, 90, 493;

    Article  CAS  Google Scholar 

  20. Angew Chem. Int. Ed. Engl. 1978, 17, 466

    Article  Google Scholar 

  21. Keim, W.; Behr, A.; Gruber, B.; Hoffmann, B.; Kowaldt, F.H.; Kürschner, U.; Limbäcker, B.; Sistig, F.P. Organometallics 1986, 5, 2356.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1991 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Keim, W. (1991). Industrial Aspects of Selectivity Applying Homogeneous Catalysis. In: Noels, A.F., Graziani, M., Hubert, A.J. (eds) Metal Promoted Selectivity in Organic Synthesis. Catalysis by Metal Complexes, vol 12. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3408-8_1

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-3408-8_1

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5508-6

  • Online ISBN: 978-94-011-3408-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics