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Diamagnetic Susceptibilities and Electronic Delocalization

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Localization and Delocalization in Quantum Chemistry

Part of the book series: Localization and Delocalization in Quantum Chemistry ((LDQC,volume 1))

Abstract

Experimental and theoretical results on the diamagnetic susceptibilities of hydrocarbons are analyzed and are correlated to electronic derealization.

In spite of the additivity rule, the interaction effects between non-bonded atoms give an important paramagnetic contribution to the saturated hydrocarbon susceptibilities.

In the case of unsaturated hydrocarbons, diamagnetism is a sensitive test for electronic derealization. However, the magnetic anisotropy in these molecules are due not only to this derealization, but also to localized contribution of sp 2-hybridized atoms.

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Authors and Affiliations

  1. Laboratoire de Chimie Physique A, Université de Bordeaux I, 351, cours de la Libération, 33405, Talence, France

    J. Hoarau

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  1. J. Hoarau
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Editors and Affiliations

  1. Centre de Mécanique Ondulatoire Appliquée du C.N.R.S., 23, rue du Maroc, Paris 19ème, France

    Odilon Chalvet  & Raymond Daudel  & 

  2. Institut de Biologie Physico-Chimique, 13, rue Pierre et Marie Curie, Paris 5ème, France

    Simon Diner  & Jean Paul Malrieu  & 

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© 1975 D. Reidel Publishing Company, Dordrecht-Holland

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Hoarau, J. (1975). Diamagnetic Susceptibilities and Electronic Delocalization. In: Chalvet, O., Daudel, R., Diner, S., Malrieu, J.P. (eds) Localization and Delocalization in Quantum Chemistry. Localization and Delocalization in Quantum Chemistry, vol 1. Springer, Dordrecht. https://doi.org/10.1007/978-94-010-1778-7_21

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  • DOI: https://doi.org/10.1007/978-94-010-1778-7_21

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-1780-0

  • Online ISBN: 978-94-010-1778-7

  • eBook Packages: Springer Book Archive

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