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Impurity Effects in Crystal Growth from Solution

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Interfacial Aspects of Phase Transformations

Part of the book series: NATO Advanced Study Institutes Series ((ASIC,volume 87))

Abstract

Impurities can affect all stages of the crystallization process. Since they simultaneously influence kinetic and thermodynamic factors, they induce, at least theoretically, conflicting effects on nucleation and growth mechanisms. Kinetics are mostly slowed down by the presence of the impurities and only a few examples are known where they enhance growth rates. Adsorption of impurities occurs in kinks, steps or on the surfaces between the steps. The impurity molecules are either separated or linked to each other in the two dimensional adsorption layers which may include solute and solvent molecules. When adsorption differs on different crystal faces, the relative growth rates of the faces can change, sometimes resulting in habit modifications. Adsorption models and parameters relevant to habit changes are reviewed and a few examples are noted.

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Author information

Authors and Affiliations

  1. Centre de Recherche sur les Mécanismes de la Croissance Cristalline, CNRS - Campus de Luminy, Case 913, 13288, Marseille - Cedex 9, France

    R. Boistelle

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  1. R. Boistelle
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Editor information

Editors and Affiliations

  1. Center for Crystal Growth - CNRS, Marseille, France

    Boyan Mutaftschiev

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© 1982 D. Reidel Publishing Company

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Boistelle, R. (1982). Impurity Effects in Crystal Growth from Solution. In: Mutaftschiev, B. (eds) Interfacial Aspects of Phase Transformations. NATO Advanced Study Institutes Series, vol 87. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-7870-6_24

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  • DOI: https://doi.org/10.1007/978-94-009-7870-6_24

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-009-7872-0

  • Online ISBN: 978-94-009-7870-6

  • eBook Packages: Springer Book Archive

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