Skip to main content

Applications of Stable Isotopes for Regional to National-Scale Water Quality and Environmental Monitoring Programs

  • Chapter
  • First Online:
Isoscapes

Abstract

Isotopes are a potentially powerful component of monitoring and assessment programs aimed at quantifying and mitigating alterations to environments from human activities. In particular, isotopic techniques have proved useful for tracing sources and sinks of various pollutants in large river basins, wetlands, and airsheds. Many of these studies have been conducted at the regional to national scale by building on existing large-scale water, air, and ecological monitoring programs managed by federal and state agencies, and demonstrate the usefulness of isotopes as a complement to standard chemical and hydrological mass balance methods. This chapter presents an overview of how nitrate, particulate organic matter, and water isotopes can be used to interpret spatial patterns and temporal changes in pollution sources, biogeochemical processes, and ecosystem function in watersheds, at the regional to national scale. Examples from several recent and ongoing studies are presented. From the insights developed using varied sampling strategies and isoscapes, we suggest guidelines for future studies in biologically active and human-impacted rivers.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 149.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 199.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 199.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Anderson C, Cabana G (2005) Delta N-15 in riverine food webs: effects of N inputs from agricultural watersheds. Can J Fish Aquat Sci 62:333–340

    Article  CAS  Google Scholar 

  • Anderson C, Cabana G (2006) Does δ15N in river food webs reflect the intensity and origin of N loads from the watershed? Sci Total Environ 367:968–978

    Article  CAS  Google Scholar 

  • Bates AL, Orem WH, Harvey JW, Spiker EC (2002) Tracing sources of sulfur in the Florida Everglades. J Environ Qual 31:287–299

    Article  CAS  Google Scholar 

  • Battaglin WA et al (2001) Chemical and isotopic evidence of nitrogen transformation in the Mississippi River, 1997–98. Hydrol Process 15:1285–1300

    Article  Google Scholar 

  • Bowen GJ (2009) Statistical and geostatistical mapping of precipitation water isotope ratios. In: West JB, Bowen GJ, Dawson T, Tu KP (eds) Isoscapes: understanding movement, pattern, and process on Earth through isotope mapping. Springer, Berlin

    Google Scholar 

  • Bullen TD, Kendall C (1998) Tracing of weathering reactions and water flowpaths: a multi-isotope approach. In: Kendall C, McDonnell JJ (eds) Isotope tracers in catchment hydrology. Elsevier Science, Amsterdam

    Google Scholar 

  • Connolly RM, Guest MA, Melville AJ, Oakes JM (2003) Sulfur stable isotopes separate producers in marine food-web analysis. Oecologia 138:161–167

    Article  Google Scholar 

  • Coplen TB, Kendall C (2000) Stable hydrogen and oxygen isotope ratios for selected sites of the US Geological Survey’s NASQAN and Benchmark surface-water networks. US Geol Surv Open-File Rep 00-160; 424

    Google Scholar 

  • Elliott EM et al (2007) Nitrogen isotopes as indicators of NOx source contributions to atmospheric nitrate deposition across the midwestern and northeastern United States. Environ Sci Technol 41:7661–7667

    Article  CAS  Google Scholar 

  • Elliott EM et al. (2009) Dual nitrate isotopes in actively and passively collected dry deposition: utility for partitioning NOx sources, understanding reaction pathways, and comparison with isotopes in wet nitrate deposition. J Geophy Res-Biogeosciences (in press)

    Google Scholar 

  • Finlay JC (2004) Patterns and controls of lotic algal stable carbon isotope ratios. Limnol Oceanogr 49:850–861

    Article  CAS  Google Scholar 

  • Finlay JC, Kendall C (2007) Stable isotope tracing of temporal and spatial variability in organic matter sources to freshwater ecosystems. In: Michener RH, Lajtha K (eds) Stable isotopes in ecology and environmental science, 2nd edn. Blackwell Publishing, p. 283–333

    Google Scholar 

  • Finlay JC, Khandwala S, Power ME (2002) Spatial scales of carbon flow in a river food web. Ecology 83:1845–1859

    Article  Google Scholar 

  • Fry B (2006) Stable isotope ecology. Springer, New York

    Book  Google Scholar 

  • Harrington RR et al (1998) 15N enrichment in agricultural catchments: field patterns and applications to tracking Atlantic salmon (Salmo salar). Chem Geol 147:281–294

    Article  CAS  Google Scholar 

  • Hebert CE, Wassenaar LI (2001) Stable nitrogen isotopes in waterfowl feathers reflect agricultural land use in western Canada. Environ Sci Technol 35:3482–3487

    Article  CAS  Google Scholar 

  • Hinckley ES, Kendall C, Loague K (2008) Not all water becomes wine: sulfur inputs as an opportune tracer of hydrochemical losses from vineyards. Water Resour Res 44:W00401. doi:10.1029/2007WR006672

    Article  Google Scholar 

  • Hitchon B, Krouse HR (1972) Hydrogeochemistry of the surface waters of the Mackenzie River drainage basin, Canada – III Stable isotopes of oxygen, carbon and sulphur. Geochim Cosmochim Acta 36:1337–1357

    Article  CAS  Google Scholar 

  • Hobson KA, Wassenaar LI (eds) (2008) Tracking animal migration with stable isotopes. Academic, Boston, MA

    Google Scholar 

  • Kendall C, Coplen TB (2001) Distribution of oxygen-18 and deuterium in river waters across the United States. Hydrol Process 15:1363–1393

    Article  Google Scholar 

  • Kendall C, McDonnell JJ (eds) (1998) Isotope tracers in catchment hydrology. Elsevier Science Publishers p. 839

    Google Scholar 

  • Kendall C, Stober QJ, Meyer P, Silva SR (1997) Spatial distributions of isotopic compositions of Gambusia and periphyton at REMAP marsh sites in the Everglades. [abs], in USGS Program on the South Florida Ecosystem. In: Proceedings of the technical symposium in Ft Lauderdale, Florida, August 25–27, 1997. USGS Open-File Report 97-385, pp 44–45

    Google Scholar 

  • Kendall C, Silva SR, Kelly VJ (2001) Carbon and nitrogen isotopic compositions of particulate organic matter in four large river systems across the United States. Hydrol Proc 15:1301–1346

    Article  Google Scholar 

  • Kendall C, Elliott EM, Wankel SD (2007) Tracing anthropogenic inputs of nitrogen to ecosystems. In: Michener RH, Lajtha K (eds) Stable isotopes in ecology and environmental science, 2nd edn. Blackwell Publishing, p. 375–449

    Google Scholar 

  • Kendall C, Young MB, Silva SR (2008) Determination of sources of organic matter and nutrients in the San Joaquin River. USGS Open File Report (unpublished)

    Google Scholar 

  • Koerner W, Dambrine E, Dupouey JL, Benoit M (1999) Delta N-15 of forest soil and understorey vegetation reflect the former agricultural land use. Oecologia 121:421–425

    Article  Google Scholar 

  • Kohzu A et al (2008) Use of stable nitrogen isotope signatures of riparian macrophytes as an indicator of anthropogenic N inputs to river ecosystems. Environ Sci Technol 42(21):7837–7841. doi:10.1021/es801113k

    Article  CAS  Google Scholar 

  • Kratzer CR et al. (2004) Sources and transport of nutrients, organic carbon, and chlorophyll-a in the San Joaquin River upstream of Vernalis, California, during summer and fall, 2000 and 2001. USGS WRI 03-4127. 124 p. http://waterusgsgov/pubs/wri/wri034127/2/2009

  • McClain ME et al (2003) Biogeochemical hot spots and hot moments at the interface of terrestrial and aquatic ecosystems. Ecosystems 6:301–312

    Article  CAS  Google Scholar 

  • Michener RH, Lajtha K (eds) (2007) Stable isotopes in ecology and environmental science, 2nd edn. Blackwell Publishers, p. 592

    Google Scholar 

  • Nagata T, Miyajima T (eds) (2008) Stable isotopes in environmental assessment of watersheds – progress towards an integrated approach. Kyoto University Press, 476 p (Japanese language)

    Google Scholar 

  • Nriagu JO et al. (1991) Hydrosphere. In: Krouse HR, Grinenko V (eds) Stable isotopes: natural and anthropogenic sulphur in the environment. SCOPE 43, Wiley, Chichester

    Google Scholar 

  • Saurer M et al (2004) First detection of nitrogen from NOx in tree rings: a 15N/14N study near a motorway. Atmos Environ 38:2779–2787

    Article  CAS  Google Scholar 

  • Stringfellow WT et al. (2008) San Joaquin River Up-Stream DO TMDL Project, ERP-02D-P63, 2321 p. http://www.eerp-pacific.org/2/2009

  • Vaccaro JJ, Maloy KJ (2006) A thermal profile method to identify potential ground-water discharge areas and preferred Salmonid habitats for long river reaches. USGS Scientific Investigations Report 2006–5136

    Google Scholar 

  • Vannote RL et al (1980) The river continuum concept. Can J Fish Aquat Sci 37:130–137

    Article  Google Scholar 

  • Volkmar EC, Dahlgren RA (2006) Biological oxygen demand dynamics in the Lower San Joaquin River, California. Environ Sci Technol 40:5653–5660

    Article  CAS  Google Scholar 

  • Wadleigh MA, Blake DM (1999) Tracing sources of atmospheric sulphur using epiphytic lichens. Environ Pollut 106:265–271

    Article  CAS  Google Scholar 

  • Wadleigh MA, Schwarcz HP, Kramer JR (1996) Isotopic evidence for the origin of sulphate in coastal rain. Tellus 48B:44–59

    CAS  Google Scholar 

  • Wang L, Okin GS, Macko SA (2009) Remote sensing of nitrogen and carbon isotope compositions in terrestrial ecosystems. In: West JB, Bowen GJ, Dawson T, Tu KP (eds) Isoscapes: understanding movement, pattern, and process on Earth through isotope mapping. Springer, Berlin

    Google Scholar 

  • Wankel SD, Kendall C, Francis CA, Paytan A (2006) Nitrogen sources and cycling in the San Francisco Bay Estuary: a nitrate dual isotopic composition approach. Limnol Oceanogr 51(4):1654–1664

    Article  CAS  Google Scholar 

  • Welker JM (2000) Isotopic (δ18O) characteristics of weekly precipitation collected across the USA: an initial analysis with application to water source studies. Hydrol Process 14:1449–1464

    Article  Google Scholar 

  • Wunder MB (2009) Using isoscapes to model probability surfaces for determining geographic origins. In: West JB, Bowen GJ, Dawson T, Tu KP (eds) Isoscapes: understanding movement, pattern, and process on Earth through isotope mapping. Springer, Berlin

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Carol Kendall .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2010 Springer Science+Business Media B.V.

About this chapter

Cite this chapter

Kendall, C., Young, M.B., Silva, S.R. (2010). Applications of Stable Isotopes for Regional to National-Scale Water Quality and Environmental Monitoring Programs. In: West, J., Bowen, G., Dawson, T., Tu, K. (eds) Isoscapes. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-3354-3_5

Download citation

Publish with us

Policies and ethics