Abstract
For a long time, MX-chain compounds have been extensively studied since Wolffram reported Cl-bridged Pt complex in 1900. To date, more than 300 compounds were reported by combining metal ions (M = Ni, Pd, Pt), bridging halogens (X = Cl, Br, I) in plane ligands (L = ethylenediamine(en), 1R,2R-diaminocyclohexane(chxn), etc.), and counteranions (ClO −4 , BF −4 , X−, etc.). However, the number of Ni compounds is very few compared to Pd or Pt compounds. The first Ni complex was reported by Yamashita et al. in 1981. Although there had been much controversy about the electronic state of these compounds, it has been clarified that this complex is in averaged valence state by means of X-ray crystal structure analysis [1]. In the Ni complexes, many attractive physical properties have been reported such as gigantic third-order nonlinear optical susceptibility [2], spin-Peierls transition [3], etc. In this chapter, we introduce structure, physical properties, and recent progresses in the Ni complexes.
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References
Toriumi K, Wada Y, Mitani T, Bandow S, Yamashita M, Fujii Y (1989) J Am Chem Soc 111:2341
Kishida H, Matsuzaki H, Okamoro H, Manabe T, Yamashita M, Taguchi Y, Tokura Y (2000) Nature 405:929
Takaishi S, Tobu Y, Kitagawa H, Goto A, Shimizu T, Okubo T, Mitani T, Ikeda R (2004) J Am Chem Soc 126:1614
Hazell A (1991) Acta Cryst C 47:962
Bonner JC, Fisher ME (1964) Phys Rev 135:A640
Eggert S, Affleck I, Takahashi M (1994) Phys Rev Lett 73:332
Dehmelt HG, Kruger H (1951) Z Physik 129:401
Smith PW, Stoessiger R (1971) J Chem Soc D 7:279
Nuclear Quadrupole Resonance Spectra Data Base, Japan Association for International Chemical Information, Apr 2003
Bayer H (1951) Z Physik 130:227
Kushida T, Benedek GB, Bloembergen N (1956) Phys Rev 104:1364
Townes CH, Dailey BP (1949) J Chem Phys 17:782
Dailey BP, Townes CH (1955) J Chem Phys 23:118
King JG, Jaccarino V (1954) Phys Rev 94:1610
Ito K, Nakamura D, Kurita Y, Ito K, Kubo M (1961) J Am Chem Soc 83:4526
Nakamura D, Kurita Y, Ito K, Kubo M (1960) J Am Chem Soc 82:5783
Ikeda R, Nakamura D, Kubo M (1965) J Phys Chem 69:2101
Okamoto H, Toriumi K, Mitani T, Yamashita M (1990) Phys Rev B 42:10381
Okamoto H, Shimada Y, Oka Y, Chainani A, Takahashi T, Kitagawa H, Mitani T, Toriumi K, Inoue K, Manabe T, Yamashita M (1996) Phys Rev B 54:8438
Tanino H, Kobayashi K (1983) J Phys Soc Jpn 52:1446
Takaishi S, Kitagawa H, Ikeda R (2002) Mol Cryst Liq Cryst 379:279
Takahashi Y, Suemoto T (2004) Phys Rev B 70:081101
Iwano K, Ono M, Okamoto H (2002) Phys Rev B 66:235103
Iwano K (2006) Phys Rev B 73:035108
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Takaishi, S., Yamashita, M. (2013). Ni(III) Mott–Hubbard Compounds. In: Yamashita, M., Okamoto, H. (eds) Material Designs and New Physical Properties in MX- and MMX-Chain Compounds. Springer, Vienna. https://doi.org/10.1007/978-3-7091-1317-2_3
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DOI: https://doi.org/10.1007/978-3-7091-1317-2_3
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