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Poly(ionic liquid)s: Designing CO2 Separation Membranes

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Applications of Ionic Liquids in Polymer Science and Technology

Abstract

Taking into account the extremely broad range of chemical and structural possibilities of ionic liquid (IL) chemistry, and the undeniable economical and engineering advantages of membrane technology, the CO2 separation performance of membranes based on poly(ionic liquid)s (PILs) is here discussed. A perspective of the different membrane-designing strategies, including neat PIL membranes having polycation backbones, PIL/IL composites, different frameworks of PIL copolymer membranes, and PIL/IL/zeolite mixed matrix membranes, will be presented. Due to the promising data obtained for this new class of functional polymers, combining some of the exceptional and unique properties of ILs with the macromolecular architecture of polymers, it is foreseen that PIL-based membranes will play a especial role in CO2 separation.

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Acknowledgments

Liliana C. Tomé would like to thank the FCT (Fundação para a Ciência e Tecnologia) for her PhD research grant (SFRH/BD/72830/2010). Isabel M. Marrucho also acknowledges FCT/MCTES (Portugal) for a contract under Investigador FCT 2012. This work was supported through the project PTDC/QEQ-FTT/1686/2012.

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  1. Instituto de Tecnologia Química e Biológica António Xavier, Universidade Nova de Lisboa, Av. República, 2780-157, Oeiras, Portugal

    Liliana C. Tomé & Isabel M. Marrucho

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  1. Liliana C. Tomé
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  2. Isabel M. Marrucho
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Correspondence to Isabel M. Marrucho .

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  1. Institute for Polymer Materials, POLYMAT, University of the Basque Country UPV/EHU, Donostia-San Sebastian, Spain

    David Mecerreyes

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Tomé, L.C., Marrucho, I.M. (2015). Poly(ionic liquid)s: Designing CO2 Separation Membranes. In: Mecerreyes, D. (eds) Applications of Ionic Liquids in Polymer Science and Technology. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-662-44903-5_10

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