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Hydrothermal Activity and its Effects on Sedimentary Organic Matter

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Bitumens in Ore Deposits

Part of the book series: Special Publication of the Society for Geology Applied to Mineral Deposits ((MINERAL DEPOS.,volume 9))

Abstract

The conversion of organic matter to petroleum products by hydrothermal activity is an easy process, occurring in nature in many types of environments. Geologically immature organic matter of marine sediments is being altered by this process to petroleum in the Guaymas Basin (Gulf of California), Escanaba Trough and Middle Valley (NE Pacific), Bransfield Strait (Antarctica), and Atlantis II Deep (Red Sea). Contemporary organic detritus and/or viable microorganisms are also converted in part to petroleum-like products when they become entrained by turbulent mixing into the discharging vent waters, resulting in instantaneous hydrous pyrolysis. This latter case is ubiquitous to all hydrothermal systems, but can be studied in hydrothermal vent fields without a sedimentary cover emanating directly from oceanic ridges, as for example on the East Pacific Rise at 13°N and 21°N and on the Mid-Atlantic Ridge at 26°N. The hydrocarbon products (methane to asphalt) generated in all these areas have been compared in terms of composition, organic matter sources, and analogy to reservoir petroleum. In addition, this type of organic matter rep¬resents a major input of carbon to the primary chemosynthetic bioproductivity of hydrothermal vent systems and may be important to interactions with the metals of hydrothermal mineral ores.

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References

  • Barrett TJ, Jambor JL (eds) (1988) Seafloor hydrothermal mineralization. Can Mineral 26: 429–888

    Google Scholar 

  • Berkowitz N, Calderon J (1990) Extraction of oil sand bitumens with supercritical water. Fuel Proc Techn 25: 33–44

    Article  Google Scholar 

  • Blumer M (1975) Curtisite, idrialite and pendletonite, polycyclic aromatic hydrocarbon minerals: their composition and origin. Chem Geol 16: 245–256

    Article  Google Scholar 

  • Blumer M (1976) Polycyclic aromatic compounds in nature. Sci Am 234: 34–45

    Article  Google Scholar 

  • Brault M, Simoneit BRT (1988) Steroid and triterpenoid distributions in Bransfield Strait sediments: Hydrothermally-enchanced diagenetic transformations. In: Advances in organic geochemistry 1987. Org Geochem 13: 697–705

    Google Scholar 

  • Brault M, Simoneit BRT (1989) Trace petroliferous organic matter associated with hydrothermal minerals from the Mid-Atlantic Ridge at the Trans-Atlantic Geotraverse 26°N site. J Geophys Res 94: 9791–9798

    Article  Google Scholar 

  • Brault M, Simoneit BRT, Marty JC, Saliot A (1985) Les hydrocarbures dans le système hydrothermal de la ride Est-Pacifique, à 13°N. CR Acad Sci Paris 301:1L•807–812

    Google Scholar 

  • Brault M, Simoneit BRT, Marty JC, Saliot A (1988) Hydrocarbons in waters and particulate material from hydrothermal environments at the East Pacific Rise, 13°N. Org Geochem 12: 209–219

    Article  Google Scholar 

  • Brault M, Simoneit BRT, Saliot A (1989) Trace petroliferous organic matter associated with massive hydrothermal sulfides from the East Pacific Rise at 13°N and 21°N. Oceanol Acta 12: 405–415

    Google Scholar 

  • Carranza-Edwards A, Rosales-Hoz L, Aguayo-Camargo JE, Lozano-Santa Cruz R, Hornelas¬Orozco Y (1990) Geochemical study of hydrothermal core sediments and rocks from the Guaymas Basin, Gulf of California. In: Simoneit BRT (ed) Organic matter alteration in hydrothermal systems — petroleum generation, migration and biogeochemistry. Appt Geochem 5: 77–82

    Google Scholar 

  • Childress JJ (ed) (1988) Hydrothermal vents, a case study of the biology and chemistry of a deep-sea hydrothermal vent of the Galapagos Rift, the Rose Garden in 1985. Deep-Sea Res 35: 1677–1849

    Google Scholar 

  • Clifton CG, Walters CC, Simoneit BRT (1990) Hydrothermal petroleums from Yellowstone National Park, Wyoming, U.S.A. In: Simoneit BRT (ed) Organic matter in hydrothermal systems — petroleum generation, migration and biogeochemistry. Appl Geochem 5: 169–191

    Google Scholar 

  • Connolly JF (1966) Solubility of hydrocarbons in water near the critical solution temperatures. J Chem Eng Data 11: 13–16

    Article  Google Scholar 

  • Corliss JB, Dymond J, Gordon LI, Edmond JM, von Herzen RP, Ballard RD, Green K, Williams D, Bainbridge A, Crane K, van Andel TH (1979) Submarine thermal springs on the Galapagos Rift. Science 203: 1073–1083

    Article  Google Scholar 

  • Curray JR, Moore DG, Aguayo JE, Aubry MP, Einsele G, Fornari DJ, Gieskes J, Guerrero JC, Kastner M, Kelts K, Lyle M, Matoba Y, Molina-Cruz A, Niemitz J, Rueda J, Saunders AD, Schrader H, Simoneit BRT, Vacquier V (1982) Initial reports of the deep sea drilling project, vol 64, Parts I and II US Government Printing Office, Washington DC, 1314 pp

    Chapter  Google Scholar 

  • Czochanska Z, Sheppard CM, Weston RJ, Woolhouse AD, Cook RA (1986) Organic geochemistry of sediments in New Zealand, Part I. A biomarker study of the petroleum seepage at the geothermal region of Waiotapu. Geochim Cosmochim Acta 50: 507–515

    Google Scholar 

  • Didyk BM, Simoneit BRT (1989) Hydrothermal oil of Guaymas Basin and implications for petroleum formation mechanisms. Nature 342: 65–69

    Article  Google Scholar 

  • Didyk BM, Simoneit BRT (1990) Petroleum characteristics of the oil in a Guaymas Basin hydrothermal chimney. In: Simoneit BRT (ed) Organic matter alteration in hydrothermal systems — petroleum generation, migration and biogeochemistry. Appl Geochem 5: 29–40

    Google Scholar 

  • Edmond JM, Von Damm K (1983) Hot springs on the ocean floor. Sci Am 248 (4): 78–93

    Article  Google Scholar 

  • Franklin JM, Lydon JW, Sangster DF (1981) Volcanic-associated massive sulfide deposits. Econ Geol 75: 485–627

    Google Scholar 

  • Geissman TA, Sim KY, Murdoch J (1967) Organic minerals. Picene and chrysene as constituents of the mineral curtisite (idrialite). Experientia 23: 793–794

    Google Scholar 

  • Gieskes JM, Elderfield H, Lawrence JR, Johnson J, Meyers B, Campbell AC (1982a) Geochemistry of interstitial waters and sediments, Leg 64, Gulf of California. In: Curray JR, Moore DG et al. (eds) Initial reports of the deep sea drilling project 64 (2): 675–694

    Google Scholar 

  • Gieskes JM, Kastner M, Einsele G, Kelts K, Niemitz J (19826) Hydrothermal activity in the Guaymas Basin, Gulf of California: A synthesis. In: Initial reports of the deep sea drilling project 64(2):1159–1168

    Google Scholar 

  • Gieskes JM, Simoneit BRT, Brown T, Shaw T, Wang T-C, Magenheim A (1988) Hydrothermal fluids and petroleum in surface sediments of Guaymas Basin, Gulf of California: a case study. Can Mineral 26: 589–602

    Google Scholar 

  • Grassle JF (1985) Hydrothermal vent animals: distribution and biology. Science 229: 713–717

    Article  Google Scholar 

  • Hartmann M (1985) Atlantis II Deep geothermal brine system. Chemical processes between hydrothermal brines and Red Sea deep water. Mar Geol 64: 157–177

    Article  Google Scholar 

  • Haymon RM, Koski R, Sinclair C (1984) Fossils of hydrothermal vent worms from Cretaceous sulfide ores of the Somail ophiolite, Oman. Science 223: 1407–1409

    Google Scholar 

  • Hunt JM (1979) Petroleum geochemistry and geology. W.H. Freeman and Company, San Francisco

    Google Scholar 

  • Jones ML (ed) (1985) Hydrothermal vents of the Eastern Pacific: an overview. Bull Biol Soc Wash 6: 1–566

    Google Scholar 

  • Josephson J (1982) Supercritical fluids. Environ Sci Technol 16: 548A - 551A

    Article  Google Scholar 

  • Kawka 0E, Simoneit BRT (1987) Survey of hydrothermally-generated petroleums from the Guaymas Basin spreading center. Org Geochem 11: 311–328

    Article  Google Scholar 

  • Kawka 0E, Simoneit BRT (1990) Polycyclic aromatic hydrocarbons in hydrothermal petroleums from the Guaymas Basin spreading center. In: Simoneit BRT (ed) Organic matter alteration in hydrothermal systems — petroleum generation, migration and biogeochemistry. Appl Geochem 5: 17–27

    Google Scholar 

  • Koski RA, Lonsdale PF, Shanks WC, Berndt ME, Howe SS (1985) Mineralogy and geochemistry of a sediment-hosted hydrothermal sulfide deposit from the southern trough of Guaymas Basin, Gulf of California. J Geophys Res 90: 6695–6707

    Google Scholar 

  • Kvenvolden KA, Simoneit BRT (1990) Hydrothermally derived petroleum: Examples from Guaymas Basin, Gulf of California and Escanaba Trough, Northeast Pacific. Am Assoc Pet Geol Bull 74: 223–237

    Google Scholar 

  • Kvenvolden KA, Rapp JB, Hostettler FD, Morton JL, King JD, Claypool GE (1986) Petroleum associated with polymetallic sulfide in sediment from Gorda Ridge. Science 234: 1231–1234

    Article  Google Scholar 

  • Kvenvolden KA, Rapp JB, Hostettler FD (1990) Hydrocarbon geochemistry of hydrothermally¬generated petroleum from Escanaba Trough, offshore California. In: Simoneit BRT (ed) Organic matter alteration in hydrothermal systems — petroleum generation, migration and biogeochemistry. Appl Geochem 5: 83–91

    Google Scholar 

  • Lonsdale P (1985) A transform continental margin rich in hydrocarbons, Gulf of California. Bull Am Assoc Pet Geol 69: 1160–1180

    Google Scholar 

  • Lonsdale P, Becker K (1985) Hydrothermal plumes, hot springs, and conductive heat flow in the Southern Trough of Guaymas Basin. Earth Planet Sci Lett 73: 211–225

    Article  Google Scholar 

  • Love JD, Good JM (1970) Hydrocarbons in thermal areas, northwestern Yellowstone National Park, Wyoming. US Geol Sury Prof Pap 7644-B

    Google Scholar 

  • Michaelis W, Jenisch A, Richnow HH (1990) Hydrothermal petroleum generation in Red Sea sediments from the Kebrit and Shaban Deeps. In: Simoneit BRT (ed) Organic matter alteration in hydrothermal systems — petroleum generation, migration and biogeochemistry. Appl Geochem 5: 103–114

    Google Scholar 

  • Peter JM (1986) Genesis of hydrothermal vent deposits in the southern trough of Guaymas Basin, Gulf of California: a mineralogical and geochemical study. M Sc Thesis, University of Toronto

    Google Scholar 

  • Peter JM, Simoneit BRT, Kawka 0E, Scott SD (1990) Liquid hydrocarbon-bearing inclusions in modern hydrothermal chimneys and mounds from the southern trough of Guaymas Basin. In: Simoneit BRT (ed) Organic matter alteration in hydrothermal systems — petroleum generation, migration and biogeochemistry. Appl Geochem 5: 51–63

    Google Scholar 

  • Peter JM, Peltonen P, Scott SD, Simoneit BRT, Kawka OE (1991) Carbon-14 ages of hydrothermal petroleum and carbonate in Guaymas Basin, Gulf of California — implications for oil generation, expulsion and migration. Geology 19: 253–256

    Google Scholar 

  • Price LC, Wenger LM, Ging T, Blount CW (1983) Solubility of crude oil in methane as a function of pressure and temperature. Org Geochem 4: 201–221

    Article  Google Scholar 

  • Rona PA (1984) Hydrothermal mineralization at seafloor spreading centers. Earth Sci Rev 20:1¬104

    Google Scholar 

  • Rona PA (1988) Hydrothermal mineralization at oceanic ridges. Can Mineral 26: 431–465

    Google Scholar 

  • Rona PA, Boström K, Laubier L, Smith KL Jr (eds) (1983) Hydrothermal processes at seafloor spreading centers, NATO Conf. Series. Plenum Press, New York, 769 pp

    Google Scholar 

  • Rona PA, Thompson G, Mottl MJ, Karson JA, Jenkins WJ, Graham D, Mallette M, Von Damm K, Edmond JM (1984) Hydrothermal activity at the Trans-Atlantic Geotraverse hydrothermal field, Mid-Atlantic Ridge Crest at 26°N. J Geophys Res 89: 11365–11377

    Article  Google Scholar 

  • Ross DS (1984) Coal conversion in carbon monoxide-water systems. Coal Sci 3: 301–337

    Google Scholar 

  • Ross DS, Hum GP, Miin T-C, Green TK, Mansini R (1986) Supercritical water/CO liquefaction and a model forr coal conversion. Fuel Proc Techn 12: 277–285

    Article  Google Scholar 

  • Sakai H, Gamo T, Kim E-S, Tsutsumi M, Tanaka T, Ishibashi J, Wakita H, Yamano M, Oomori T (1990) Venting of carbon dioxide-rich fluid and hydrate formation in mid-Okinawa Trough backarc basin. Science 248: 1093–1096

    Article  Google Scholar 

  • Sanders ND (1986) Visual observation of the solubility of heavy hydrocarbons in near-critical water. Ind Eng Chem Fundam 25: 169–171

    Article  Google Scholar 

  • Scott LT (1982) Thermal rearrangements of aromatic compounds. Acc Chem Res 15: 52–58

    Article  Google Scholar 

  • Scott SD (1985) Seafloor polymetallic sulfide deposits: modern and ancient. Mar Min 5: 191–212

    Google Scholar 

  • Shock EL (1988) Organic acid metastability in sedimentary basins. Geology 16: 886–890

    Article  Google Scholar 

  • Shock EL (1989) Corrections to “Organic acid metastability in sedimentary basins.” Geology 17: 572–573

    Google Scholar 

  • Shock EL (1990) Chemical constraints on the origin of organic compounds in hydrothermal systems. Orig Life Evol Biosphere 20: 331–367

    Article  Google Scholar 

  • Simoneit BRT (1985a) Hydrothermal petroleum: Genesis, migration and deposition in Guaymas Basin, Gulf of California. Can J Earth Sci 22: 1919–1929

    Article  Google Scholar 

  • Simoneit BRT (1985b) Hydrothermal petroleum: Composition and utility as a biogenic carbon source. In: Jones ML (ed) Hydrothermal vents of the eastern Pacific: an Overview. Bull Biol Soc Wash 6: 49–56

    Google Scholar 

  • Simoneit BRT (ed) (1990) Organic matter in hydrothermal systems — petroleum generation, migration and biogeochemistry. Appl Geochem 5: 1–248

    Google Scholar 

  • Simoneit BRT, Galimov EM (1984) Geochemistry of interstitial gases in Quaternary sediments of the Gulf of California. Chem Geol 43: 151–166

    Article  Google Scholar 

  • Simoneit BRT, Philp RP, Jenden PD, Galimov EM (1984) Organic geochemistry of Deep Sea Drilling Project sediments from the Gulf of California — hydrothermal effects on unconsolidated diatom ooze. Org Geochem 7: 173–205

    Article  Google Scholar 

  • Simoneit BRT, Grimalt JO, Hayes JM, Hartman H (1987) Low temperature hydrothermal maturation of organic matter in sediments from the Atlantis H Deep, Red Sea. Geochim Cosmochim Acta 51: 879–894

    Google Scholar 

  • Simoneit BRT, Kawka 0E, Brault M (1988) Origin of gases and condensates in the Guaymas Basin hydrothermal system. In: Schoell M (ed) Origins of methane in the Earth. Chem Geol 71: 169–182

    Google Scholar 

  • Simoneit BRT, Brault M, Saliot A (1990) Hydrocarbons associated with hydrothermal minerals, vent waters and talus on the East Pacific Rise and Mid-Atlantic Ridge. In: Simoneit BRT (ed) Organic matter alteration in hydrothermal systems — petroleum generation, migration and biogeochemistry. Appl Geochem 5: 115–124

    Google Scholar 

  • Simoneit BRT, Kawka 0E, Wang G-M (1992) Biomarker maturation in contemporary hydrothermal systems, alteration of immature organic matter in zero geological time. In: Moldowan J, Philp RP, Albrecht P (eds) Biological markers in sediments and petroleum Prentice Hall, Englewood Cliffs, NJ, chapt. 7, pp 124–141.

    Google Scholar 

  • Suess E, Simoneit BRT, Wefer G, Whiticar MJ, Fisk M, von Breymann M, Han MW, Wittstock R, Laban C, Kadko D, Top Z (1992) Hydrothermalism in the Bransfield Strait, Antarctica. Geol Rundsch (in prep)

    Google Scholar 

  • Tiercelin J-J, Thourin C, Kalala T, Mondergeur A (1989) Discovery of sublacustrine hydrothermal activity and associated massive sulfides and hydrocarbons in the north Tanganyika trough, East African Rift. Geology 17: 1053–1056

    Google Scholar 

  • Tissot BP, Weite DH (1984) Petroleum formation and occurrence: a new approach to oil and gas exploration, 2nd edn. Springer, Berlin Heidelbeig New York Tödheide K (1982) Hydrothermal solutions. Ber Bunsenges Phys Chem 86:1005–1016

    Google Scholar 

  • Von Damm KL (1990) Seafloor hydrothermal activity: Black smoker chemistry and chimneys. Ann Rev Earth Planet Sci 18: 173–204

    Article  Google Scholar 

  • Welhan JA, Lupton JE (1987) Light hydrocarbon gases in Guaymas Basin hydrothermal fluids: thermogenic versus abiogenic origin. Am Assoc Pet Geol Bull 71: 215–223

    Google Scholar 

  • Whelan JK, Simoneit BRT, Tarafa M (1988) C,—05 hydrocarbons in sediments from Guaymas Basin, Gulf of California — comparison to Peru Margin, Japan Trench and California Borderlands. Org Geochem 12: 171–194

    Google Scholar 

  • Whiticar MJ, Suess E, Wehner H (1985) Thermogenic hydrocarbons in surface sediments of the Bransfield Strait, Antarctic Peninsula. Nature 314: 87–90

    Google Scholar 

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© 1993 Springer-Verlag Berlin Heidelberg

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Simoneit, B.R.T. (1993). Hydrothermal Activity and its Effects on Sedimentary Organic Matter. In: Parnell, J., Kucha, H., Landais, P. (eds) Bitumens in Ore Deposits. Special Publication of the Society for Geology Applied to Mineral Deposits, vol 9. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-85806-2_6

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  • DOI: https://doi.org/10.1007/978-3-642-85806-2_6

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