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IR-Overtone Vibration Spectroscopy

  • Chapter
Intermolecular Forces

Abstract

Some advantages to study intermolecular forces by IR overtone spectra are reported. The overtone intensity is nearly insensitive on interactions contrary to the large intensity increase of fundamental bands. As consequence H-bond equilibria and the structure of H-bonded liquids can be studied easier and in some directions with higher precision. Secondly, the simultaneous excitation of two H-bonded molecules by one quantum and this possibility to study H-bonds are shown. The determination of dipole moment changes by intermolecular interactions is described based on overtone spectra. Last but not least the possibilities to study van der Waals interactions in condensed media are given.

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Authors
  1. W. P. Luck
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Editors and Affiliations

  1. Department Scheikunde, Katholieke Universiteit Leuven, B-3030, Leuven (Haverlee), Belgium

    Pierre L. Huyskens  & Therese Zeegers-Huyskens  & 

  2. Physikalische Chemie und Zentrum für Materialwissenschaften, Philipps Universität, D-3550, Marburg, West-Germany

    Werner A. P. Luck

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© 1991 Springer-Verlag Berlin, Heidelberg

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Luck, W.P. (1991). IR-Overtone Vibration Spectroscopy. In: Huyskens, P.L., Luck, W.A.P., Zeegers-Huyskens, T. (eds) Intermolecular Forces. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-76260-4_7

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  • DOI: https://doi.org/10.1007/978-3-642-76260-4_7

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-76262-8

  • Online ISBN: 978-3-642-76260-4

  • eBook Packages: Springer Book Archive

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