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Ultrafast Photodecomposition of Dibenzoyl Peroxide studied by Time-Resolved Infrared Spectroscopy

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Book cover Ultrafast Phenomena XVI

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 92))

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Abstract

The photodissociation of dibenzoyl peroxide is controlled by its S1-lifetime and in 0.4 ps leads to a benzoyloxy/phenyl radical pair plus CO2 via concerted bond breakage of the O-O and the phenyl-C(carbonyl) bond.

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References

  1. K. Fujimori, in Organic Peroxides, Edited by W. Ando, Wiley, New York, 1992.

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  2. B. Abel, J. Assmann, M. Buback, M. Kling, R. Oswald, S. Schmatz, J. Schroeder, and T. Witte, J. Phys. Chem. A 107, 5157, 2003.

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  3. C. Reichardt, J. Schroeder, P. Vöhringer, and D. Schwarzer, Phys. Chem. Phys. 10. 1662, 2008.

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Authors and Affiliations

  1. AG Reaktionsdynamik, Max-Planck-Institut für biophysikalische Chemie, Am Fassberg 11, 37077, GÖttingen, Germany

    C. Reichardt, T. Schäfer & D. Schwarzer

  2. Institut für Physikalische Chemie, Georg-August-Universität GÖttingen, Tammannstraße 6, 37077, GÖttingen, Germany

    J. Schroeder

  3. LS Molekulare Physikalische Chemie, Institut für Physikal.& Theoret. Chemie, Universität Bonn, Wegelerstr. 12, 53115, Bonn, Germany

    P. VÖhringer

Authors
  1. C. Reichardt
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  2. T. Schäfer
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  3. J. Schroeder
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  4. P. VÖhringer
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  5. D. Schwarzer
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Corresponding author

Correspondence to D. Schwarzer .

Editor information

Editors and Affiliations

  1. National Research Council Canada, Sussex Drive 100, Ottawa, K1A 0R6, Canada

    Paul Corkum

  2. Dipto. Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano, 20133, Italy

    Sandro Silvestri

  3. Technology (MIT), Massachusetts Institute of, Massachusetts Ave. 77, Cambridge, 02139, USA

    Keith A. Nelson

  4. Sektion Physik, Univ. München, Oettingenstr. 67, München, 80538, Germany

    Eberhard Riedle

  5. Lawrence Berkeley National Laboratory, University of California, Cyclotron Road 1, Berkeley, 94720, USA

    Robert W. Schoenlein

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© 2009 Springer-Verlag Berlin Heidelberg

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Reichardt, C., Schäfer, T., Schroeder, J., VÖhringer, P., Schwarzer, D. (2009). Ultrafast Photodecomposition of Dibenzoyl Peroxide studied by Time-Resolved Infrared Spectroscopy. In: Corkum, P., Silvestri, S., Nelson, K., Riedle, E., Schoenlein, R. (eds) Ultrafast Phenomena XVI. Springer Series in Chemical Physics, vol 92. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-540-95946-5_159

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  • DOI: https://doi.org/10.1007/978-3-540-95946-5_159

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-95945-8

  • Online ISBN: 978-3-540-95946-5

  • eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)

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