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Advanced Materials pp 155–165Cite as

Mössbauer Study of the Effect of Mechanical Activation on the Magnetic Properties of PbFe0.5Nb0.5O3

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Part of the book series: Springer Proceedings in Physics ((SPPHY,volume 193))

Abstract

Mössbauer studies of PbFe0.5Nb0.5O3 samples prepared by mechanical activation of PbO, Fe2O3 and Nb2O5 mixture and subsequent sintering at various temperatures T S were performed. The room temperature Mössbauer spectra consist of two doublets (D1 and D2) for the samples with T S  < 800 °C and one doublet (D1) for the samples with T S  > 800 °C. The parameters of the doublet D1 correspond to Fe3+ in the octahedron environment. Doublet D2 has a lower isomer shift corresponding to Fe3+ with the coordination number 5 that indicates the presence of oxygen vacancies. Dependence of the temperature T N of magnetic phase transition on T S has a maximum at T S ≈ 700 °C. The effect of Fe3+/Nb5+ ordering degree and oxygen deficiency on T N is discussed.

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Acknowledgements

This work was partially supported by Ministry of Education and Science of the Russian Federation (Research project No. 3.5346.2017/BP), Russian Foundation for Basic Research (project 17–03–01293_a) and Research Committee of the University of Macau under Research & Development Grant for Chair Professor No RDG007/FST-CHD/2012.

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Authors and Affiliations

  1. Faculty of Physics, Research Institute of Physics, Southern Federal University, Rostov-on-Don, Russia

    S. P. Kubrin, I. P. Raevski, V. V. Stashenko, D. A. Sarychev, V. V. Titov & S. I. Raevskaya

  2. Institute of Solid State Chemistry and Mechanochemistry SB RAS, Novosibirsk, Russia

    A. A. Gusev & V. P. Isupov

  3. University of Macau, Macau, China

    H. Chen

  4. National Taiwan University of Science and Technology, Taipei, Taiwan, China

    C. -C. Chou

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  1. S. P. Kubrin
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  5. V. P. Isupov
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Correspondence to I. P. Raevski .

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Editors and Affiliations

  1. Mathematics, Mechanics and Computer Sciences Institute, Southern Federal University Math., Mech. and CS Inst., Rostov-on-Don, Russia

    Ivan A. Parinov

  2. Department of Microelectronics Engineering, National Kaohsiung Marine University Dept. of Microelectronics Eng., Kaohsiung, Taiwan

    Shun-Hsyung Chang

  3. Fakultas Teknik, University of 17 Agustus 1945 Surabaya , Surabaya, Indonesia

    Muaffaq A. Jani

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Kubrin, S.P. et al. (2017). Mössbauer Study of the Effect of Mechanical Activation on the Magnetic Properties of PbFe0.5Nb0.5O3 . In: Parinov, I., Chang, SH., Jani, M. (eds) Advanced Materials. Springer Proceedings in Physics, vol 193. Springer, Cham. https://doi.org/10.1007/978-3-319-56062-5_14

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