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Visible Light Photoredox Catalyzed Trifluoromethylation-Ring Expansion via Semipinacol Rearrangement

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Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks

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Abstract

Fluorine, with ground state electronic configuration [He]2s22p5, is the first member of the halogen series (Group 9) in the periodic table. It also has the second smallest atomic radius after hydrogen (rw = 1.47 and 1.20 Å, respectively) and it is the most electronegative element in the periodic table; electronically, fluorine is more similar to its neighbor oxygen (Pauling scale: χ(F): 4.0 and χ(O): 3.5) than other halogens.

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  1. Angewandte Homogenkatalyse, LIKAT Rostock, Rostock, Germany

    Dr. Basudev Sahoo

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  1. Dr. Basudev Sahoo
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Correspondence to Basudev Sahoo .

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Sahoo, B. (2017). Visible Light Photoredox Catalyzed Trifluoromethylation-Ring Expansion via Semipinacol Rearrangement. In: Visible Light Photocatalyzed Redox-Neutral Organic Reactions and Synthesis of Novel Metal-Organic Frameworks. Springer Theses. Springer, Cham. https://doi.org/10.1007/978-3-319-48350-4_3

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