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Enhancing the Performance of Mg–Al Brine Water Batteries Using Conductive Polymer-PEDOT:PSS

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ICREGA’14 - Renewable Energy: Generation and Applications

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Abstract

In this paper, the effect of the conductive additive, poly (3, 4-ethylenedioxythiophene)-poly (styrene sulfonate) (PEDOT:PSS) on brine water batteries was investigated. Brine water batteries were produced using magnesium powder mixed with aluminum powder, activated carbon and carbon nanotube, which functioned as the anode with aluminum foil as the current collector. The aluminum current collector also took part in the anodic reaction after the magnesium was used up in the brine water battery reaction. AgCl mixed with activated carbon and carbon nanotubes functioned as the cathode. Platinum mesh was used as current collector for the cathode. The binder used was a mixture of poly vinyl alcohol and poly acrylic acid. To this binder, the conductive binder PEDOT:PSS was added. The brine water battery consisted of five cells in series connection and each cell had an anode and cathode either with or without PEDOT:PSS. The brine water batteries were operated in a 3.5 % NaCl which mimics sea water.

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References

  1. F.L. Mantia, M. Pasta, H.D. Deshazer, B.E. Logan, Y. Cui, Batteries for efficient energy extraction from a water salinity difference. Nano Lett. 11(4), 1810–1813 (2011)

    Article  Google Scholar 

  2. T. Zhang, Z. Tao, J. Chen, Magnesium-air batteries: from principle to application. Mater. Horiz. (2014). doi: 10.1039/C3MH00059A

  3. S. Ono, K. Asami, T. Osaka, N. Masuko, Structure of anodic films on magnesium. J. Electrochem. Soc. 143(3), L62–L63 (1996)

    Article  Google Scholar 

  4. R.F. Koontz, R.D. Lucero, Magnesium water-activated batteries, in Handbook of Batteries, ed. by D. Linden, T.B. Reddy (McGraw-Hill, New York, 2002), pp. 17.1–17.27

    Google Scholar 

  5. J.A. Hunter, W.B. O’Callaghan, G.M. Scamans, Aluminium Batteries. US Patent 4942100, 17 July 1990

    Google Scholar 

  6. M.G. Medeiros, E.G. Dow, Magnesium-solution phase catholyte seawater electrochemical system. J. Power Sources 80(1–2), 78–82 (1999)

    Article  Google Scholar 

  7. Ø. Hasvold, H. Henriksen, E. Melvær, G. Citi, B.Ø. Johansen, T. Kjønigsen, R. Galetti, Sea water battery for subsea control systems. J. Power Sources 65(1–2), 253–261 (1997)

    Article  Google Scholar 

  8. B. Winther-Jensen, M. Gaadingwe, D.R. Macfarlane, M. Forsyth, Control of magnesium interfacial reactions in aqueous electrolytes towards a biocompatible battery. Electrochim. Acta 53(20), 5881–5884 (2008)

    Article  Google Scholar 

  9. Y. Yang, G. Yu, J.J. Cha, H. Wu, M. Vosgueritchian, Y. Yao, Z. Bao, Y. Cui, Improving the performance of lithium sulfur batteries by conductive polymer coating. ACS Nano 5(11), 9187–9193 (2011)

    Article  Google Scholar 

  10. Z. Hongyang, B. Pei, J. Dongying, Electrochemical performance of magnesium alloy and its application on the sea water battery. J. Environ. Sci. 21(suppl. 1), S88–S91 (2009)

    Google Scholar 

  11. L. Wang, P. Li, L. He, Effect of adding different contents of mercury to magnesium on discharge and corrosion performances of magnesium anode sheet. Russ. J. Electrochem. 47(8), 900–907 (2011)

    Article  Google Scholar 

  12. Y. Kun, H. Qiao, Z. Jun, D. Yu-long, Electrochemical properties of magnesium alloy anodes discharged in seawater. Trans. Nonferrous Met. Soc. China 22(9), 2184–2190 (2012)

    Article  Google Scholar 

  13. A. Borenstien, M. Noked, S. Okashy, D. Aurbach, Composite carbon nano-tubes (CNT)/activated carbon electrodes for non-aqueous super capacitors using organic electrolyte solutions. J. Electrochem. Soc. 160(8), A1282–A1285 (2013)

    Article  Google Scholar 

  14. Y. Ma, N. Li, D. Li, M. Zhang, X. Huang, Performance of Mg–14Li–1Al–0.1Ce as anode for Mg-air battery. J. Power Sources 196(4), 2346–2350 (2011)

    Article  MathSciNet  Google Scholar 

  15. Y. Lv, M. Liu, Y. Xu, D. Cao, J. Feng, The electrochemical behaviors of Mg-8Li-3Al-0.5Zn andMg-8Li-3Al-1.0Zn in sodium chloride solution. J. Power Sources 225, 124–128 (2013)

    Article  Google Scholar 

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Acknowledgments

We acknowledge the support of EMAL Company for their financial support.

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Correspondence to Y. Haik .

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Abdulrehman, T., Yousif, Z.A., Al-Ameri, S., Abdulkareem, I., Abdulla, A.M., Haik, Y. (2014). Enhancing the Performance of Mg–Al Brine Water Batteries Using Conductive Polymer-PEDOT:PSS. In: Hamdan, M., Hejase, H., Noura, H., Fardoun, A. (eds) ICREGA’14 - Renewable Energy: Generation and Applications. Springer Proceedings in Energy. Springer, Cham. https://doi.org/10.1007/978-3-319-05708-8_52

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  • DOI: https://doi.org/10.1007/978-3-319-05708-8_52

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