Abstract
Variotherm injection molding processes are used to increase the quality of molded parts. Currently, tempering systems exhibit low temperature gradients or require additional process steps. A heating system applied directly on the cavity surface of the mold tool combines two benefits: high temperature gradients without additional process steps. In this study, a heating coating made of TiOx/Cr2O3 was applied on the surface of a tooling steel to control the cavity temperature by Joule heating. The heating coating is electrically insulated from the substrate by an Al2O3 coating. Homogeneity of temperature distribution was investigated as well as thermal durability for processing polyamide in the temperature range from 70 °C to 220 °C. The coating system withstood 5,000 thermal cycles at high heating rates and without degradation.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Bonten, C.: Kunststofftechnik: Einführung und Grundlagen (Plastics Technology: Introduction and Basics). Einführung und Grundlagen, 1st edn. Carl Hanser Fachbuchverlag, München (2014)
Johannaber, F., Michaeli, W.: Handbuch Spritzgießen. Carl Hanser Verlag GmbH & Co. KG, München (2004)
Moayyedian, M., Abhary, K., Marian, R.: Gate design and filling process analysis of the cavity in injection molding process. Adv. Manuf. (2016). https://doi.org/10.1007/s40436-016-0138-5
Tredoux, L., Satoh, I.: Investigation of wave-like flow marks in injection molding: flow visualization and micro-geometry. Polymer Eng. Sci. 39, 2233–2241 (1999)
Giessauf, J., Pillwein, G., Steinbichler, G.: Werkzeugtemperierung: die variotherme temperierung wird produktionstauglich (mold temperature control: variotherm temperature control is fit for production). Kunststoffe 98, 87–92 (2008)
Prudenziati, M.: Development and the Implementation of High-Temperature Reliable Heaters in Plasma Spray Technology. J. Therm. Spray Technol. (2008). https://doi.org/10.1007/s11666-008-9164-6
Luth, J., Winkelmann, M., Wüst, F., Hartmann, S., Trenkle, F., Krieg, P., Killinger, A.: Thin, metallic heating coatings, manufactured by means of suspension spraying. Thermal Spray Bull. 12, 72–76 (2019)
Scheitz, S., Toma, F.-L., Berger, L.-M., Puschmann, R., Sauchuck, V., Kusnezoff, M.: Thermally sprayed multilayer ceramic heating elements. Thermal Spray Bull. 11, 88–92 (2011)
Berger, L.-M., Toma, F.-L., Scheitz, S., Trache, R., Börner, T.: Thermisch gespritzte Schichten im System Al2O3-Cr2O3-TiO2 - ein Update. Mat.-wiss. u. Werkstofftech (2014). https://doi.org/10.1002/mawe.201400260
Trache, R., Berger, L.-M., Toma, F.-L., Saaro, S., Lima, R., Marple, B.: Electrical resistivity of thermally sprayed Cr2O3-TiO2 coatings. In: Conference Proceedings: Int. Thermal Spray Conference, 27–29 September 2011, Hamburg (2011)
Hayfield, P.C.S.: Electrode material, electrode and electrochemical cell Patent US4422917, 27 December 1983
Berger, L.-M., Stahr, C.C., Saaro, S., Thiele, S., Woydt, M., Kelling, N.: Dry sliding up to 7.5 m/s and 800 °C of thermally sprayed coatings of the TiO2–Cr2O3 system and (Ti,Mo)(C,N)–Ni(Co). Wear (2009). https://doi.org/https://doi.org/10.1016/j.wear.2008.12.105
Wang, C.C., Akbar, S.A., Madou, M.J.: Ceramic Based Resistive Sensors. J. Electroceram. 2, 273–282 (1998)
Bobzin, K., Wietheger, W., Knoch, M.A., Schacht, A.: Heating behaviour of plasma sprayed TiOx/Cr2O3 coatings for injection moulding. Surf. Coat. Technol. (2020). https://doi.org/10.1016/j.surfcoat.2020.126199
Liu, Y., West, A.R.: Semiconductor-Insulator Transition in Undoped Rutile, TiO2 Ceramics. J. Am. Ceram. Soc. (2013). https://doi.org/10.1111/jace.12025
Acknowledgement
The presented investigations were carried out at RWTH Aachen University within the framework of the Collaborative Research Centre SFB1120-236616214 “Precision Melt Engineering” and funded by the Deutsche Forschungsgemeinschaft e.V. (DFG, German Research Foundation). The sponsorship and support is gratefully acknowledged.
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2021 The Author(s), under exclusive license to Springer Nature Switzerland AG
About this paper
Cite this paper
Bobzin, K., Wietheger, W., Heinemann, H., Schacht, A. (2021). TiOx/Cr2O3 Heating Coatings for Injection Molding of Polyamide. In: Reisgen, U., Drummer, D., Marschall, H. (eds) Enhanced Material, Parts Optimization and Process Intensification. EMPOrIA 2020. Lecture Notes in Mechanical Engineering. Springer, Cham. https://doi.org/10.1007/978-3-030-70332-5_8
Download citation
DOI: https://doi.org/10.1007/978-3-030-70332-5_8
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-70331-8
Online ISBN: 978-3-030-70332-5
eBook Packages: EngineeringEngineering (R0)