Metal-Containing Polymeric Systems

1. Front Matter

   Pages i-x

   PDF

2. Metal-Containing Polymers: An Introduction

   • Charles E. Carraher Jr., Charles U. Pittman Jr.

   Pages 1-42

3. The Synthesis and Polymerization of Vinyl Organometallic Monomers

   • M. D. Rausch, D. W. Macomber, K. Gonsalves, F. G. Fang, Z.-R. Lin, C. U. Pittman Jr.

   Pages 43-57

4. Models for Highly Phenylated Transition Metal-Containing Polymers: Derivatives of the Pentaphenylcyclopentadienyl Ligand

   • D. W. Slocum, S. Duraj, M. Matusz, J. L. Cmarik, K. M. Simpson, D. A. Owen

   Pages 59-68

5. Ferrocene Polymers

   • Cr. Simionescu, Tatiana Lixandru, Lucia Tataru, I. Mazilu, M. Vata, D. Scutaru

   Pages 69-81

6. Use of Organometallic Polymers for Pre-Heat Shields for Targets in Inertial-Confinement Nuclear Fusion

   • John E. Sheats, Fred Hessel, Louis Tsarouhas, Kenneth G. Podejko, Thomas Porter, L. B. Kool et al.

   Pages 83-98

7. Hydrophilic Macromolecular Ferricenium Salts — Part I: Preparative and Spectroscopic Features of Selected Mononuclear Ferricenium Compound

   • Eberhard W. Neuse

   Pages 99-136

8. Polymer Bound Bimetallic Complexes as Surface Reactants on Semiconductor Electrodes

   • Thomas E. Bitterwolf

   Pages 137-147

9. Synthesis and Properties of Cationic Cyclopentadienyl Iron (II) Moiety Supported on Polystyrene Beads

   • Enrique A. Roman, Gerardo J. Valenzuela, Ramon O. Latorrre, John E. Sheats

   Pages 149-164

10. Modification of Dextran through Reaction with Biscyclopentadienyltitanium Dichloride Employing the Interfacial Condensation Technique

    • Yoshinobu Naoshima, Charles E. Carraher Jr., George G. Hess, Masahide Kurokawa

    Pages 165-181

11. Electron Microscopic Studies of Osmium Carbohydrate Polymers

    • C. C. Hinckley, S. Sharif, L. D. Russell

    Pages 183-195

12. Biological Activities of Monomeric and Polymeric Derivatives of cis-Dichlorodiamineplatinum II

    • Charles E. Carraher Jr., Claredine Ademu-John, David J. Giron, John J. Fortman

    Pages 197-212

13. Structural Characterization of cis-Platinum II Derivatives of Polyethyleneimine as a Model Carrier for Natural Drug Carriers

    • Charles E. Carraher Jr., Claredine Ademu-John, John J. Fortman, David J. Giron

    Pages 213-223

14. Organotin Piezo- and Pyroelectric Polymer Films

    • R. Liepins, M. L. Timmons, N. Morosoff, J. Surles

    Pages 225-235

15. Nuclear Magnetic Resonance as a Probe of Organic Conductors

    • Larry J. Azevedo

    Pages 237-248

16. Polymer-Metal Complexes for Solar Energy Conversion

    • Masao Kaneko, Akira Yamada

    Pages 249-274

17. Conducting Organometallic Polymers and Organometallic Complexes Containing M(CO)3 (Diene) Groups

    • Hajime Yasuda, Ippei Noda, Yoshitsugu Morita, Hitoshi Nakamura, Seiichi Miyanaga, Akira Nakamura

    Pages 275-290

18. Polymers Containing Polynuclear Cobalt and Iron Carbonyl Complexes

    • J. C. Gressier, G. Levesque, H. Patin, F. Varret

    Pages 291-302

19. Decomposition of Iron Carbonyls in Solid Polymer Matrices: Preparation of Novel Metal-Polymer Composites

    • R. Tannenbaum, E. P. Goldberg, C. L. Flenniken

    Pages 303-339

20. Microemulsion; Surfactant Vesicle and Polymerized Surfactant Vesicle Entrapped Colloidal Catalysts and Semiconductors: Preparation, Characterization, and Utilization

    • Janos H. Fendler, Kazue Kurihara

    Pages 341-353

Research on metal-containing polymers began in the early 1960's when several workers found that vinyl ferrocene and other vinylic transition metal u -com­ plexes would undergo polymerization under the same conditions as conventional organic monomers to form high polymers which incorporated a potentially reactive metal as an integral part of the polymer structures. Some of these materials could act as semi-conducters and pos­ sessed one or two dimensional conductivity. Thus appli­ cations in electronics could be visualized immediately. Other workers found that reactions used to make simple metal chelates could be used to prepare polymers if the ligands were designed properly. As interest in homo­ geneous catalysts developed in the late 60's and early 70's, several investigators began binding homogeneous catalysts onto polymers, where the advantage of homo­ geneous catalysis - known reaction mechanisms and the advantage of heterogeneous catalysis - simplicity and ease of recovery of catalysts could both be obtained. Indeed the polymer matrix itself often enhanced the selectivity of the catalyst.

• colloid
• nuclear magnetic resonance
• polymer
• reactant
• synthesis

• Rider College, Lawrenceville, USA

  John E. Sheats

• Wright State University, Dayton, USA

  Charles E. Carraher

• Mississippi State University, Mississippi State, USA

  Charles U. Pittman

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