Abstract
Tris(4-chlorophenyl)methanol and tris(4-chlorophenyl)methane have been detected as microcontaminants in the marine environment since 1989 (Walker et al. 1989). Several abbreviations are used for these compounds, such as 4,4′,4″-TCP, TCP, TCPM, and TCPM-OH for tris(4-chlorophenyl)methanol and 4,4,′ 4″-TCPMe, TCPMe, and 4,4,′4″-TCPM for tris(4-chlorophenyl)methane. In this paper, the abbreviations TCPM and TCPMe are used. TCPM and TCPMe (Fig. 1) are structurally related to DDT and dicofol (l,l,l-trichloro-2,2-bis(4-chlorophenyl)methanol (Fig. 2).
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References
Buser HR (1995) DDT, a potential source of environmental tris(4-chlorophenyl)methanol. Environ Sci Technol 29:2133–2139.
de Boer J (1995) Analysis and biomonitoring of complex mixtures of persistent halogenated micro-contaminants. Ph.D. thesis, Free University, Amsterdam, The Netherlands.
de Boer J, Wester PG, Evers EHG, Brinkman UAT (1996) Determination of tris(4-chlorophenyl)methanol and tris(4-chlorophenyl)methane in fish, marine mammals and sediment. Environ Pollut 93:39–47.
Duinker JC, Hillebrand MT, Zeinstra T, Boon JP (1989) Individual chlorobiphenyls and pesticides in tissues of some cetacean species from the North Sea and the Atlantic Ocean: tissue distribution and biotransformation. Aquat Mamm 15: 95–124.
Hansch C, Leo AJ (1979) Substituent constants for correlation analysis in chemistry and biology. Wiley, New York.
Hoogenboom LAP (1996) Salmonella/microsome test with tris(4-chlorophenyl)-methanol and tris(4-chlorophenyl)methane. Rep LHO.RIK.95.04. RIKILT-DLO, Wageningen, The Netherlands.
Jarman WM, Simon M, Norstrom RJ, Bruns SA, Bacon CA, Simaret BRT, Riseborough RW (1992) Global distribution of tris(4-chlorophenyl)methanol in high trophic level birds and mammals. Environ Sci Technol 26:1770–1774.
Michaels GB, Lewis DL (1985) Sorption and toxicity of azo and triphenylmethane dyes to aquatic microbial populations. Environ Toxicol Chem 4:45–50.
Michaels GB, Lewis DL (1986) Microbial transformation rates of azo and triphenylmethane dyes. Environ Toxicol Chem 5:161–166.
Norstrom R, Simon M (1988) Presence of tris(chlorophenyl)methanol in Canadian environmental tissue samples. Rep CRD-88–7. Canadian Wildlife Service, Chemistry Research Division, Hull, Québec, Canada.
Olsson A, Bergman A (1995) A new persistent contaminant detected in Baltic wildlife: bis(4-chlorophenyl)sulfone. Ambio 24:119–123.
Rahman MS, Montanarella L, Johansson B, Larsen B (1993) Trace levels of tris(4-chlorophenyl)methanol and -methane in human milk. Chemosphere 27:1487–1497.
Walker W, Riseborough RW, Jarman WM, Lappe BW, Lappe JA, Tefft JA, de Long RL (1989) Identification of tris (chlorophenylmethanol) in blubber of harbour seals from Puget Sound. Chemosphere 18:1799–1804.
Wester PG, de Boer J, Brinkman UAT (1996) Determination of polychlorinated terhenyls in aquatic biota and sediment with gas chromatography/mass spectrometry using negative chemical ionisation. Environ Sci Technol 30:473–480.
Zook DR, Buser HR, Bergqvist PA, Rappe C, Olsson A (1992) Detection of tris(4-chlorophenyl) methanol in ringed seal (Phoca hispida) from the Baltic Sea. Ambio 21:557–560.
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© 1997 Springer-Verlag
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de Boer, J. (1997). Environmental Distribution and Toxicity of Tris(4-Chlorophenyl)Methanol and Tris(4-Chlorophenyl)Methane. In: Ware, G.W. (eds) Reviews of Environmental Contamination and Toxicology. Reviews of Environmental Contamination and Toxicology, vol 150. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-2278-1_4
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DOI: https://doi.org/10.1007/978-1-4612-2278-1_4
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