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Definition
Diamond-like carbon (DLC) coatings are defined as a metastable form of amorphous carbon (a-C) or hydrogenated amorphous carbon (a-C:H) containing a significant fraction of sp3 bonds. Hydrogen-free DLCs with the highest density and sp3 content are called tetrahedral amorphous carbon (ta-C) and its hydrogenated analog ta-C:H. It is convenient to display the compositions of the various forms of amorphous C-H alloys on a ternary phase diagram, as shown in Fig. 1 (Ferrari and Robertson 2000; Robertson 2002). DLC coatings have a high mechanical hardness, chemical inertness, and optical transparency, and it is a wide band gap semiconductor. DLC coatings are widely used as protective coatings, for instance, on optical windows, magnetic storage disks, car parts, biomedical coatings, bearings and micro-electromechanical devices (MEMs) (Robertson 2002).
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Zhang, Z., Luo, J. (2013). Diamond-Like Carbon Coatings. In: Wang, Q.J., Chung, YW. (eds) Encyclopedia of Tribology. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-92897-5_720
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