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Computational and Instrumental Methods in EPR

  • Book
  • © 2007

Overview

Authors:
  1. Christopher J. Bender

    1. Department of Chemistry, Fordham University, Bronx, USA

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    You can also search for this author in PubMed   Google Scholar

  2. Lawrence J. Berliner

    1. Department of Chemistry & Biochemistry, University of Denver, Denver, USA

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  • The first comprehensive volume to offer practical, non-invasive spectroscopic methods of analyzing the rheology of biopolymers: comparative studies of polymer fluidity using traditional methods (e.g. viscosity) and nuclear magnetic resonance

Part of the book series: Biological Magnetic Resonance (BIMR, volume 25)

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Table of contents (5 chapters)

  1. Front Matter

    Pages i-xiii
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  2. Microwave Amplitude Modulation Technique to Measure Spin-Lattice (T 1) and Spin-Spin (T 2) Relaxation Times

    • Sushil K. Misra
    Pages 1-29

  3. Improvement in the Measurement of Spin-Lattice Relaxation Time in Electron Paramagnetic Resonance

    • Robert Lopez
    Pages 31-82

  4. Quantitative Measurement of Magnetic Hyperfine Parameters and the Physical Organic Chemistry of Supramolecular Systems

    • Christopher J. Bender
    Pages 83-141

  5. New Methods of Simulation of Mn(II) EPR Spectra: Single Crystals, Polycrystalline and Amorphous (Biological) Materials

    • Sushil K. Misra
    Pages 143-177

  6. Density Matrix Formalism of Angular Momentum in Multi-Quantum Magnetic Resonance

    • H. Watari, Y. Shimoyama
    Pages 179-191

  7. Back Matter

    Pages 193-218
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About this book

Electron magnetic resonance in the time domain has been greatly facilitated by the introduction of novel resonance structures and better computational tools, such as the increasingly widespread use of density-matrix formalism. This second v- ume in our series, devoted both to instrumentation and computation, addresses - plications and advances in the analysis of spin relaxation time measurements. Chapters 1 deals with the important problem of measuring spin relaxation times over a broad temporal range. The author, Dr. Sushil Misra, has worked on a wide variety of solutions to problems in this area, with respect to both experimental and theoretical aspects, and Chapter 1 summarizes much of his recent work, which was enhanced by a fruitful collaboration with the late Professor Jacques Pescia. Chapter 2 presents solutions to the problem of measuring short spin relaxation times. Again, in collaboration and tribute to the late Jacques Pescia's laboratory, part of the chapter represents a translation of the amplitude modulation technique section from a doctoral thesis by Robert Lopez in 1993 to The Paul Sabatier U- versity. Experimental data that appeared in the original thesis are placed at the end of subsections that correspond to the described technique. Chapter 3 takes up the problem of multi-frequency ENDOR and ESEEM, and illustrates how small stepwise increments of spectrometer operating parameters can enable one to better determine spin-Hamiltonian parameters via a graphical analysis.

Authors and Affiliations

  • Department of Chemistry, Fordham University, Bronx, USA

    Christopher J. Bender

  • Department of Chemistry & Biochemistry, University of Denver, Denver, USA

    Lawrence J. Berliner

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