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Physical Properties of Polymers pp 51–133Cite as

Polyelectrolytes in solution

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Part of the book series: Advances in Polymer Science ((POLYMER,volume 120))

Abstract

This review should demonstrate that polyelectrolyte solutions are currently advancing to a fascinating topic in polymer science. The increasing effort in analytical theory, simulations and experiments is about to result in a deeper, fundamental understanding of the interacting macroions and of the conformational properties of flexible polyions. As these “simple” problems have still not been completely solved, new challenges have already emerged, such as the effect of polyion chain architecture (polyelectrolyte stars, combs, rings, μ-gels), the effect of bivalent or multivalent metal ions bound to the polyelectrolyte chain (intramolecular cross-linking, polyion coil collapse), and the complex field of surfactant-polyion and polyanion-polycation complexes. In comparison with the growing technical importance of such complex ionic systems, the fundamental academic research in this area has hardly started yet.

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Authors and Affiliations

  1. Max Plauch Institut für Kolloid- und Greuzflächenforschung, D-14513, Teltow-Seehof, FRG

    S. Förster

  2. Makromolekulare Chemie II, Universität Bayreuth, D-95440, Bayreuth, FRG

    M. Schmidt

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Dedicated to Prof. Walther Burchard on the occasion of his 65th Birthday

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Förster, S., Schmidt, M. (1995). Polyelectrolytes in solution. In: Physical Properties of Polymers. Advances in Polymer Science, vol 120. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-58704-7_2

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  • DOI: https://doi.org/10.1007/3-540-58704-7_2

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