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Benzyne-Zirconocene Reagents as Tools in Phosphorus Chemistry

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New Aspects in Phosphorus Chemistry I

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 220))

Abstract

The use of η 2-benzyne and η 2-phosphabenzyne zirconocene in phosphorus chemistry is reviewed. The regiospecific reactions of these complexes with small unsaturated organic molecules incorporating phosphorus or not led to a variety of cyclic neutral or zwitterionic complexes showing a versatile behavior. New methodologies of synthesis of phosphorus heterocycles and of phosphorus ligands are described, as well as strategies of C-H and M-H (M=N, O, P, S) bond activations.

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Authors and Affiliations

  1. Laboratoire de Chimie de Coordination CNRS, 205 route de Narbonne, 31077, Toulouse Cedex 04, France

    Jean-Pierre Majoral, Alain Igau & Victor Cadierno

  2. Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, Sienkiewicza 112, 90-363, Lodz, Poland

    Maria Zablocka

Authors
  1. Jean-Pierre Majoral
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  2. Alain Igau
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  3. Victor Cadierno
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  4. Maria Zablocka
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Editors and Affiliations

  1. Laboratoire de Chimie de Coordination du CNRS, 205, route de Narbonne, 31077, Toulouse, Cedex 4, France

    Jean-Pierre Majoral (Directeur de Recherche) (Directeur de Recherche)

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© 2002 Springer-Verlag Berlin Heidelberg

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Majoral, JP., Igau, A., Cadierno, V., Zablocka, M. (2002). Benzyne-Zirconocene Reagents as Tools in Phosphorus Chemistry. In: Majoral, JP. (eds) New Aspects in Phosphorus Chemistry I. Topics in Current Chemistry, vol 220. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-45731-3_3

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  • DOI: https://doi.org/10.1007/3-540-45731-3_3

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-42246-4

  • Online ISBN: 978-3-540-45731-2

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