Abstract
Results from numerous studies of unperturbed dimensions for vinyl polymers are tabulated for the first time. A comparison is made between results from theta temperature measurement and those estimated from measurements in good solvents. Data for poly(1-pentene)38 was used by the authors to obtain Figs. 2ā5. This data had not previously been used to obtain estimates of the uperturbed dimensions. It is concluded that these estimation procedures are generally quite acceptable, giving values usually within 8% of those determined in theta solvents. Statistical calculations for the dependence of the unperturbed dimensions on stereoregularity are considered in the light of the available data. The calculations predict an increase in the characteristic ratio, Cā, at intermediate tacticities for vinylidene polymers whereas a decrease is predicted for vinyl polymers. It is shown that little experimental data currently exists to confirm these predictions. It is pointed out that this is not a result of insufficient experimental studies, but rather insufficient characterization of those polymers which were studied.
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Jenkins, R., Porter, R.S. (1980). Unperturbed dimensions of stereoregular polymers. In: Properties of Polymers. Advances in Polymer Science, vol 36. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-10204-3_1
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DOI: https://doi.org/10.1007/3-540-10204-3_1
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