Abstract
This chapter gives a summary of the recent findings on electron-mediated scalar couplings across hydrogen bonds. The main emphasis is put on a discussion of the various types and sizes of such couplings which have been detected in biological macromolecules. Various experimental schemes for the detection of H-bond couplings are summarized and possible applications are suggested.
This chapter is an updated version of an article previously published as “Scalar couplings across hydrogen bonds” by S. Grzesiek, F. Cordier, and A.J. Dingley, Methods in Enzymology (2001), 338, 111–133. Reprinted by permission of the publisher.
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Grzesiek, S., Cordier, F., Dingley, A.J. (2002). Hydrogen Bond Scalar Couplings — A New Tool In Biomolecular NMR. In: Krishna, N.R., Berliner, L.J. (eds) Protein NMR for the Millennium. Biological Magnetic Resonance, vol 20. Springer, Boston, MA. https://doi.org/10.1007/0-306-47936-2_9
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