Skip to main content
Log in

Experimental study on rheological properties of vegetable oils mixed with titanium dioxide nanoparticles

  • Technical Paper
  • Published:
Journal of the Brazilian Society of Mechanical Sciences and Engineering Aims and scope Submit manuscript

Abstract

The paper focuses on studying the rheological properties of different vegetable oils mixed with TiO2 nanoparticles. The rheological tests of vegetable oils are conducted on cone and plate geometry of Anton Paars rheometer (MCR-102). TiO2 nanoparticles are added in 0.5 wt%, 1 wt% and 1.5 wt% concentration. The density of nanofluids is measured from 20–80 °C, and the viscosity of nanofluids is measured at temperatures of 40 °C, 70 °C and 100 °C. All the nanofluids depict Newtonian behaviour at different temperatures and are quantified by power law. The introduction of nanoparticles in the oils leads to the increase in viscosity with 1.5 wt% TiO2 concentration displaying maximum increase in viscosity in all the bio-oils. The variation of viscosity with temperature, shear rate and particle volume fraction is observed, and the measured values of viscosity are correlated with the existing theoretical viscosity models.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

Abbreviations

U :

Experimental viscosity (mm2/s) at 40 °C

Y :

Experimental viscosity (mm2/s) at 100 °C

\(\phi\) :

Solid volume fraction

\(W_{\text{n}}\) :

Weight percentage of nanoparticles (g)

\(W_{\text{o}}\) :

Weight of base oil (ml)

\(\rho_{\text{n}}\) :

Density of nanoparticles

\(\rho_{\text{o}}\) :

Density of oil

\(\tau\) :

Shear stress (Pa)

\(\gamma\) :

Shear strain (1/s)

\(k\) :

Consistency index

\(n\) :

Power law index

\(\eta_{\text{r }}\) :

Relative viscosity of fluid

\(\mu_{\text{nf}}\) :

Dynamic viscosity of nanofluid

\(\mu_{\text{bf}}\) :

Dynamic viscosity of base fluid

References

  1. Salimon J, Salih N, Yousif E (2010) Biolubricants: raw materials, chemical modifications and environmental benefits. Eur J Lipid Sci Technol 112(5):519–530

    Google Scholar 

  2. Schneider MP (2006) Plant–oil-based lubricants and hydraulic fluids. J Sci Food Agric 86(12):1769–1780

    Article  Google Scholar 

  3. Jayadas N, Nair KP (2006) Coconut oil as base oil for industrial lubricants—evaluation and modification of thermal, oxidative and low temperature properties. Tribol Int 39(9):873–878

    Article  Google Scholar 

  4. Fox N, Stachowiak G (2007) Vegetable oil-based lubricants—a review of oxidation. Tribol Int 40(7):1035–1046

    Article  Google Scholar 

  5. Shafi WK, Raina A, Ul Haq MI (2018) Friction and wear characteristics of vegetable oils using nanoparticles for sustainable lubrication. Tribol Mater Surf Interfaces 12(1):27–43

    Article  Google Scholar 

  6. Jayadas N, Nair KP, Ajithkumar G (2007) Tribological evaluation of coconut oil as an environment-friendly lubricant. Tribol Int 40(2):350–354

    Article  Google Scholar 

  7. Yu H-l, Yi X, Shi P-j, Xu B-s, Wang X-l, Qian L (2008) Tribological properties and lubricating mechanisms of Cu nanoparticles in lubricant. Trans Nonferr Met Soc China 18(3):636–641

    Article  Google Scholar 

  8. Trajano MF, Moura EIF, Ribeiro KSB, Alves SM (2014) Study of oxide nanoparticles as additives for vegetable lubricants. Mater Res 17(5):1124–1128

    Article  Google Scholar 

  9. Charoo M, Wani MF (2017) Tribological properties of h-BN nanoparticles as lubricant additive on cylinder liner and piston ring. Lubr Sci 29(4):241–254

    Article  Google Scholar 

  10. Raina A, Anand A (2017) Tribological investigation of diamond nanoparticles for steel/steel contacts in boundary lubrication regime. Appl Nanosci 7(7):371–388. https://doi.org/10.1007/s13204-017-0590-y

    Article  Google Scholar 

  11. Shafi WK, Raina A, Ul Haq MI (2018) Tribological performance of avocado oil containing copper nanoparticles in mixed and boundary lubrication regime. Ind Lubr Tribol 70:865–871

    Article  Google Scholar 

  12. Afshari A, Akbari M, Toghraie D, Yazdi ME (2018) Experimental investigation of rheological behavior of the hybrid nanofluid of MWCNT–alumina/water (80%)–ethylene-glycol (20%). J Therm Anal Calorim 132(2):1001–1015

    Article  Google Scholar 

  13. Esfe MH, Saedodin S, Wongwises S, Toghraie D (2015) An experimental study on the effect of diameter on thermal conductivity and dynamic viscosity of Fe/water nanofluids. J Therm Anal Calorim 119(3):1817–1824

    Article  Google Scholar 

  14. Ruhani B, Toghraie D, Hekmatifar M, Hadian M (2019) Statistical investigation for developing a new model for rheological behavior of ZnO–Ag (50%–50%)/Water hybrid Newtonian nanofluid using experimental data. Phys A 525:741–751

    Article  Google Scholar 

  15. Esfe MH, Afrand M, Gharehkhani S, Rostamian H, Toghraie D, Dahari M (2016) An experimental study on viscosity of alumina-engine oil: effects of temperature and nanoparticles concentration. Int Commun Heat Mass Transf 76:202–208

    Article  Google Scholar 

  16. Esfe MH, Afrand M, Rostamian SH, Toghraie D (2017) Examination of rheological behavior of MWCNTs/ZnO-SAE40 hybrid nano-lubricants under various temperatures and solid volume fractions. Exp Therm Fluid Sci 80:384–390

    Article  Google Scholar 

  17. Esfe MH, Afrand M, Yan W-M, Yarmand H, Toghraie D, Dahari M (2016) Effects of temperature and concentration on rheological behavior of MWCNTs/SiO2 (20–80)-SAE40 hybrid nano-lubricant. Int Commun Heat Mass Transf 76:133–138

    Article  Google Scholar 

  18. Shahsavar A, Khanmohammadi S, Toghraie D, Salihepour H (2019) Experimental investigation and develop ANNs by introducing the suitable architectures and training algorithms supported by sensitivity analysis: measure thermal conductivity and viscosity for liquid paraffin based nanofluid containing Al2O3 nanoparticles. J Mol Liq 276:850–860

    Article  Google Scholar 

  19. Pak BC, Cho YI (1998) Hydrodynamic and heat transfer study of dispersed fluids with submicron metallic oxide particles. Exp Heat Transfer 11(2):151–170. https://doi.org/10.1080/08916159808946559

    Article  Google Scholar 

  20. Kole M, Dey T (2011) Effect of aggregation on the viscosity of copper oxide–gear oil nanofluids. Int J Therm Sci 50(9):1741–1747

    Article  Google Scholar 

  21. Hernández Battez A, Viesca J, González R, García A, Reddyhoff T, Higuera-Garrido A (2014) Effect of shear rate, temperature, and particle concentration on the rheological properties of ZnO and ZrO2 nanofluids. Tribol Trans 57(3):489–495

    Article  Google Scholar 

  22. Nasser RM, Ahmed NS, Nassar AM (2016) Eco-friendly bio-based lube oil additiveS. Pet Coal 58(6):687–694

    Google Scholar 

  23. Yalcin H, Toker OS, Dogan M (2012) Effect of oil type and fatty acid composition on dynamic and steady shear rheology of vegetable oils. J Oleo Sci 61(4):181–187

    Article  Google Scholar 

  24. Esfe MH, Arani AAA (2018) A study on rheological characteristics of hybrid nano-lubricants containing MWCNT-TiO2 nanoparticles. J Mol Liq 260:229–236

    Article  Google Scholar 

  25. Brinkman H (1952) The viscosity of concentrated suspensions and solutions. J Chem Phys 20(4):571

    Article  Google Scholar 

  26. Batchelor G (1977) The effect of Brownian motion on the bulk stress in a suspension of spherical particles. J Fluid Mech 83(1):97–117

    Article  MathSciNet  Google Scholar 

  27. Kitano T, Kataoka T, Shirota T (1981) An empirical equation of the relative viscosity of polymer melts filled with various inorganic fillers. Rheol Acta 20(2):207–209

    Article  Google Scholar 

  28. Chong J, Christiansen E, Baer A (1971) Rheology of concentrated suspensions. J Appl Polym Sci 15(8):2007–2021

    Article  Google Scholar 

  29. Aberoumand S, Jafarimoghaddam A, Moravej M, Aberoumand H, Javaherdeh K (2016) Experimental study on the rheological behavior of silver-heat transfer oil nanofluid and suggesting two empirical based correlations for thermal conductivity and viscosity of oil based nanofluids. Appl Therm Eng 101:362–372

    Article  Google Scholar 

  30. Sajeeb A, Rajendrakumar PK (2019) Investigation on the rheological behavior of coconut oil based hybrid CeO2/CuO nanolubricants. Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology 233(1):170–177

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. S. Charoo.

Additional information

Technical Editor: Cezar Negrao, PhD.

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shafi, W.K., Charoo, M.S. Experimental study on rheological properties of vegetable oils mixed with titanium dioxide nanoparticles. J Braz. Soc. Mech. Sci. Eng. 41, 431 (2019). https://doi.org/10.1007/s40430-019-1905-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s40430-019-1905-6

Keywords

Navigation