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Hydrothermal synthesis of a new zinc phosphite (C5H7N2)2·[Zn3(HPO3)4] with intersecting 8- and 12-ring channels

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Abstract

Using 4-aminopyridine as the structure-directing agent(SDA), a new open-framework zinc phosphite, (C5H7N2)2·[Zn3(HPO3)4](ZnHPO-CJ70), was synthesized under hydrothermal condition. Single-crystal X-ray diffraction analysis reveals that ZnHPO-CJ70 is constructed by the strictly alternating ZnO4 tetrahedra and HPO3 pseudo-pyramids, with their vertexes linked to generate a three-dimensional(3D) open framework with intersecting 8- and 12-ring channels. Further characterizations of ZnHPO-CJ70 were performed by means of X-ray powder diffraction(XRD), elemental analysis(ICP, CHN), infrared spectroscopy(IR) and thermogravimetric(TG) analyses. The results of luminescent test shows that ZnHPO-CJ70 exhibits strong fluorescence emissions in the solid state at room temperature.

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Authors and Affiliations

  1. Key Lab of Groundwater Resources and Environment, Ministry of Education, College of Environment and Resources, Jilin University, Changchun, 130021, P. R. China

    Zhaojun Dong, Wenqing Zhang & Yu Wang

  2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Zhaojun Dong, Yan Yan & Jiyang Li

Authors
  1. Zhaojun Dong
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  2. Yan Yan
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  3. Wenqing Zhang
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  4. Yu Wang
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  5. Jiyang Li
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Corresponding authors

Correspondence to Yu Wang or Jiyang Li.

Additional information

Supported by the National Natural Science Foundation of China (No.21271081).

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Dong, Z., Yan, Y., Zhang, W. et al. Hydrothermal synthesis of a new zinc phosphite (C5H7N2)2·[Zn3(HPO3)4] with intersecting 8- and 12-ring channels. Chem. Res. Chin. Univ. 31, 498–502 (2015). https://doi.org/10.1007/s40242-015-5021-6

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  • DOI: https://doi.org/10.1007/s40242-015-5021-6

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