Abstract
We studied enhanced interfacial adhesion between a flexible amorphous polymer (polystyrene, PS) and a semi-crystalline polymer (a polyamide, Ny6). The surface modification of PS to provide functional groups reacting with the functional groups of Ny6 was carried out with ion-beam and/or plasma treatment. These surface modifications were found to significantly alter the interfacial adhesion strength between PS and Ny6. Though the fracture toughness was varied depending on the process, its overall behavior was quite similar with one another; the fracture toughness increased with increasing bonding temperature and bonding time, passed through a peak, and then decreased with further increase of the bonding time or temperature.
References
Seo Y, Ninh TH, Hong SM, Kim S, Kang TJ, Kim H, Kim J (2006) In Situ Compatibilizer-Reinforced Interface between a Flexible Polymer (a Functionalized Polypropylene) and a Rodlike Polymer (a Thermotropic Liquid Crystalline Polymer). Langmuir 22:3062
Seo Y, Tran HN (2004) Enhanced interfacial adhesion between polypropylene and nylon 6 by in situ reactive compatibilization. Polymer 45:8573
Kim H, Seo Y (2003) Effect of Surface Modification on the Interfacial Tension between the Melts of High-Density Polyethylene and Nylon 66: Correlation between Rheology and Morphology. Langmuir 19:2696
Kim HJ, Lee K, Seo Y, Kwak S, Koh S (2001) HDPE Surface Functionalization by Low-Energy Ion-Beam Irradiation under a Reactive O2 Environment and Its Effect on the HDPE/Nylon 66 Blend. Macromolecules 34:2546
Seo Y, Ninh TH, Hong SM, Kim S, Kang TJ, Kim H, Kim J (2006) In Situ Compatibilizer-Reinforced Interface between a Flexible Polymer (a Functionalized Polypropylene) and a Rodlike Polymer (a Thermotropic Liquid Crystalline Polymer). Langmuir 22:3062
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Seo, Y., Hong, S.M. Reactive Interfacial Adhesion Between an Amorphous Polymer (Surface-Modified Polystyrene) and a Semicrystalline Polymer (Polyamide (Nylon 6)). Int J Mater Form 3 (Suppl 1), 583–586 (2010). https://doi.org/10.1007/s12289-010-0837-6
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DOI: https://doi.org/10.1007/s12289-010-0837-6