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Fabrication of MgAl2Si2O8 : M0.01 (M = Ni2+, Cu2+, Pd2+, Pt2+ and Ru3+): catalytic effects for the reduction of 2- or 4-nitroanilines in water

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Abstract

Five new MgAl2Si2O8 : M0.01 (M = Ni2+, Cu2+, Pd2+, Pt2+ and Ru3+) materials were developed for the reduction of nitroarenes as catalysts by conventional solid state reaction at 1300∘C. The prepared materials were characterized by thermal analysis, Fourier transform infrared spectroscopy, X-ray powder diffraction analysis, scanning electron microscopy, energy-dispersive X-ray analysis and nitrogen adsorption–desorption analysis. The catalytic activities of the prepared catalysts were tested in the reduction of 2- or 4-nitroanilines in aqueous media at ambient temperature in the presence of NaBH4 by UV–vis spectrophotometer. Furthermore, the MgAl2Si2O8 : M0.01 catalysts can be recovered by filtration and reused for five cycles for the reduction of 2-nitroaniline. These results show that the MgAl2Si2O8 : M0.01 catalysts can be used in practical applications in the reduction of nitroanilines.

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Acknowledgement

We acknowledge the financial support granted by Erciyes University (ERUBAP).

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Electronic Supplementary Material

Supplementary material pertaining to this article is available on the Bulletin of Materials Science website (www.ias.ac.in/matersci).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Erciyes University, Kayseri, 38039, Turkey

    SERKAN DAYAN, SEVGI ÖZTÜRK, NILGÜN KAYACI & NILGUN KALAYCIOGLU OZPOZAN

  2. Karamanoglu Mehmetbey University, Faculty of Engineering, Department of Materials Science and Engineering, TR-70200, Karaman, Turkey

    ESRA ÖZTÜRK

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  1. SERKAN DAYAN
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  2. SEVGI ÖZTÜRK
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  3. NILGÜN KAYACI
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Correspondence to NILGUN KALAYCIOGLU OZPOZAN.

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DAYAN, S., ÖZTÜRK, S., KAYACI, N. et al. Fabrication of MgAl2Si2O8 : M0.01 (M = Ni2+, Cu2+, Pd2+, Pt2+ and Ru3+): catalytic effects for the reduction of 2- or 4-nitroanilines in water. Bull Mater Sci 38, 1651–1663 (2015). https://doi.org/10.1007/s12034-015-0981-1

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  • DOI: https://doi.org/10.1007/s12034-015-0981-1

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